210691-22-8Relevant articles and documents
Molecularly defined palladium(0) monophosphine complexes as catalysts for efficient cross-coupling of aryl chlorides and phenylboronic acid
Andreu,Zapf,Beller
, p. 2475 - 2476 (2000)
Various 1,6-diene palladium(0) monophosphine complexes have been prepared from tmedaPd(CH3)2, PR3, and the corresponding 1,6-diene. These molecularly defined Pd complexes catalyzed the Suzuki coupling of aryl chlorides wit
Hepta-1,6-diene and diallyl ether complexes of palladium(0) and platinum(0): A route to L-M(alkene)2 complexes containing non-activated alkenes
Krause, Jochen,Haack, Karl-Josef,Cestaric, Guenter,Goddard, Richard,Poerschke, Klaus-Richard
, p. 1291 - 1292 (2007/10/03)
With hepta-1,6-diene and diallyl ether, Pd0 and Pt0 form highly reactive homoleptic dinuclear M2(1,6-diene)3 complexes, which are cleaved by donors L (e.g. C2H4, phosphanes, phosphites, isonitriles) to afford mononuclear derivatives L-M(1,6-diene); the X-ray structure of (Me3P)Pd{(η2-CH2=CHCH2) 2O} has been determined.