211187-95-0Relevant articles and documents
Sodium borohydride-nickel chloride-methanol catalytic system for regioselective reduction of electron-rich conjugated dienes and reductive cleavage of allyl esters involving π-allylnickel intermediates
Yin, Biao-Lin,Cai, Cong-Bi,Lai, Jin-Qiang,Zhang, Ze-Ren,Huang, Li,Xu, Li-Wen,Jiang, Huan-Feng
supporting information; experimental part, p. 3319 - 3324 (2012/01/30)
The regioslective reduction of electron-rich dienes to monoolefins and the reductive cleavage of allyl esters were fulfilled by employing a sodium borohydride-nickel chloride-methanol catalytic system with exceedingly simple manipulations and high functional group tolerability. Both of the reductive reactions may involve π-allylnickel intermediates generated from fresh nickel boride. Copyright
