21129-18-0

Basic information

• Product Name: manganese dipropionate
• Synonyms: manganese dipropionate;Propanoic acid, manganese(2+) salt;Bispropionic acid manganese(II) salt;Dipropionic acid manganese(II) salt
• CAS NO: 21129-18-0
• Molecular Formula: 2C₃H₅O₂*Mn
• Molecular Weight: 201.079249
• EINECS: 244-229-6
• Product Categories: Organic-metal salt
• Mol File: 21129-18-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 141.7°Cat760mmHg
• Flash Point: 57.7°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 4.23mmHg at 25°C
• CAS DataBase Reference: manganese dipropionate(CAS DataBase Reference)
• NIST Chemistry Reference: manganese dipropionate(21129-18-0)
• EPA Substance Registry System: manganese dipropionate(21129-18-0)

Safety Data

• Hazardous Substances Data: 21129-18-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C3H6O2.Mn/c1-2-3(4)5;/h2H2,1H3,(H,4,5);/p-1

Upstream product

• 7439-96-5 manganese 
• 802294-64-0 propionic acid 
• 638-38-0 manganese(II) acetate 
• 6156-78-1 manganese (II) acetate tetrahydrate 
• 17496-08-1 ammonium propionate 
• 7773-01-5 manganese(ll) chloride 

Downstream Products

• 192586-99-5 Mn⁽³⁺⁾*C₁₇H₁₆N₂O₂^(2-)*O₂CC₂H₅^(1-) = [Mn(C₁₇H₁₆N₂O₂)(O₂CC₂H₅)] 
• 192586-87-1 Mn⁽³⁺⁾*C₁₇H₁₄Br₂N₂O₂^(2-)*O₂CC₂H₅^(1-) = [Mn(C₁₇H₁₄Br₂N₂O₂)(O₂CC₂H₅)] 

Relevant articles and documents

Metal carboxylate salts

A dietary source of mineral in the form of a metal carboxylate is prepared using the acid-base-like reaction. A salt of a carboxylate anion and a by-product cation is reacted in aqueous solution with a salt of a metal cation and a by-product anion under conditions which form a metal carboxylate and the by-product salt. Solutions formed in the reaction may be applied directly to a dry carrier to produce a dry dietary supplement or, alternatively, the solutions may be filtered to remove precipitated by-product salt and the filtrate used as a liquid dietary supplement. Preferably, a reducing agent, such as ascorbic acid, is added to help prevent the oxidation of divalent to trivalent form of a metal salt, when an easily oxidized divalent metal is used as starting material.

Thermal decomposition of freeze-dried μ-oxo-carboxylates of manganese and iron

The decomposition of freeze-dried mixed carboxylates of manganese and iron was investigated by means of DTA, TG, mass spectroscopy and X-ray powder diffractometry. The three main steps of decomposition are characterized as release of (a) H2O, (b) carboxylic acid and CO2/CO, and (c) the corresponding carbonyl compound and CO2. In particular, the course of process (b) strongly depends on the stability of the metal-carboxylate link in the three investigated carboxylates. Well-crystallized single-phase manganese ferrites can be obtained on decomposition of formates of appropriate composition and thermal treatment of decomposition products at 600°C while maintaining a p(O2) within the coexistence field of manganese ferrite.

Metal propionate synthesis of magnetoresistive La1-x(Ca,Sr)xMnO3 thin films

A flexible chemical solution deposition (CSD) method for the preparation of magnetoresistive La1-x(CaySr)xMnO3 thin films based completely on metal propionates is presented. A number of polycrystalline thin films with varying stoichiometries were deposited on different substrate materials at temperatures between 550° and 850°C. The crystallization behavior on selected substrates was found to depend on the thin film stoichiometry. Magnetoresistivity and magnetization were measured as a function of temperature. For the selected samples, a magnetic Curie temperature TC, a metal-semiconductor transition, and magnetoresistive behavior were observed. These measurements demonstrated that La1-x(CaySr)xMnO3 thin films with properties well known from films deposited by PLD or sputtering can be prepared by a simple, propionate-besed CSD method.