211292-60-3Relevant articles and documents
Preparation method of secondary aromatic amine
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Paragraph 0024, (2021/03/31)
The invention provides a method for preparing secondary aromatic amine by performing a palladium-catalyzed C-N coupling reaction on (pseudo)aryl halide and (pseudo)heterocyclic aryl halide and primary(heterocyclic)aromatic amine. The method is characterized in that an alkali for promoting the reaction is an alkali metal carboxylate or an alkali metal bicarbonate.
Palladium-Catalyzed Synthesis of Diarylamines and 1- and 2-Oxygenated Carbazoles: Total Syntheses of Natural Alkaloids Clauraila A, Clausenal, Clausine P, and 7-Methoxy- O -methylmukonal
Hernández-Benitez, R. Israel,Zárate-Zárate, Daniel,Delgado, Francisco,Tamariz, Joaquín
, p. 4357 - 4371 (2017/09/13)
The scope and limitations of the strategy for the conversion of 2-anilinocyclohexenones and N -arylcyclohexane enaminones into the 1- and 2-oxygenated carbazole scaffolds, respectively, were evaluated. The one-pot palladium(0)-catalyzed aromatization/meth
(N-heterocyclic carbene)PdCl2(TEA) complexes: Studies on the effect of the "throw-away" ligand in catalytic activity
Chen, Ming-Tsz,Vicic, David A.,Turner, Michael L.,Navarro, Oscar
experimental part, p. 5052 - 5056 (2011/10/31)
The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented.