211676-00-5

Basic information

• Product Name: Benzenesulfonamide, N-methyl-N-(2-methylphenyl)-4-nitro-
• CAS NO: 211676-00-5
• Molecular Formula: C14H14N2O4S
• Molecular Weight: 306.342
• Mol File: 211676-00-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-methyl-N-(2-methylphenyl)-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-methyl-N-(2-methylphenyl)-4-nitro-(211676-00-5)
• EPA Substance Registry System: Benzenesulfonamide, N-methyl-N-(2-methylphenyl)-4-nitro-(211676-00-5)

Safety Data

• Hazardous Substances Data: 211676-00-5(Hazardous Substances Data)

Upstream product

• 98-74-8 4-Nitrobenzenesulfonyl chloride 
• 95-53-4 o-toluidine 
• 186581-53-3 diazomethane 
• 109847-18-9 4-nitro-N-(2-tolyl)benzenesulfonamide 
• 6319-45-5 N-methyl-4-nitro-benzenesulfonamide 
• 108-88-3 toluene 

Downstream Products

• 3406-75-5 2-(4-nitrophenylthio)acetic acid 
• 611-21-2 N,2-dimethylaniline 

Relevant articles and documents

Study on Radical Amidation onto Aromatic Rings with (Diacyloxyiodo)arenes

Sulfonamides of primary amines bearing an aromatic ring at the γ-position were treated with (diacyloxyiodo)arenes and iodine under irradiation conditions with a tungsten lamp to give the corresponding 1,2,3,4-tetrahydroquinoline derivatives in moderate to good yields. Here, the reactivity depends on the Z-group (protecting group) of the starting amides. Under the same reaction conditions, some sulfonamides were treated with (diacetoxyiodo)benzene and iodine in the presence of aromatics to give the corresponding N-arylated amides. These reactions proceed through the intramolecular and intermolecular amidations onto aromatic rings via the sulfonamidyl radicals formed.