21175-42-8Relevant articles and documents
Cascade Synthesis of Five-Membered Lactones using Biomass-Derived Sugars as Carbon Nucleophiles
Yamaguchi, Sho,Matsuo, Takeaki,Motokura, Ken,Miyaji, Akimitsu,Baba, Toshihide
, p. 1731 - 1737 (2016)
We report the cascade synthesis of five-membered lactones from a biomass-derived triose sugar, 1,3-dihydroxyacetone, and various aldehydes. This achievement provides a new synthetic strategy to generate a wide range of valuable compounds from a single bio
MnO2-promoted carboesterification of alkenes with anhydrides: A facile approach to γ-lactones
Wu, Lihuan,Zhang, Zhenming,Liao, Jianhua,Li, Jianxiao,Wu, Wanqing,Jiang, Huanfeng
supporting information, p. 2628 - 2631 (2016/02/18)
An efficient carboesterification of alkenes with anhydrides promoted by MnO2 has been developed to afford functionalized γ-lactones in good to excellent yields. This method shows a broad substrate scope and provides a valuable and convenient synthetic tool for constructing γ-lactones.
Mn(OAc)3-mediated arylation-lactonization of alkenoic acids: Synthesis of γ,γ-disubstituted butyrolactones
Gao, Yuzhen,Xu, Jian,Zhang, Pengbo,Fang, Hua,Tang, Guo,Zhao, Yufen
, p. 36167 - 36170 (2015/05/05)
A general method for the oxidative cyclization of 4-alkenoic acids with arylboronic acids has been developed. The reactions described provide a novel access to γ,γ-disubstituted butyrolactones in moderate yields, and allow the direct formation of a C-C bo