2123-85-5

Basic information

• Product Name: 4-NITROPHENYL ACRYLATE
• Synonyms: P-NITROPHENYL ACRYLATE;4-NITROPHENYL ACRYLATE;(4-nitrophenyl) prop-2-enoate;acrylic acid (4-nitrophenyl) ester
• CAS NO: 2123-85-5
• Molecular Formula: C₉H₇NO₄
• Molecular Weight: 193.16
• Product Categories: monomer
• Mol File: 2123-85-5.mol
• Article Data: 15

Chemical Properties

• Melting Point: 61°C
• Boiling Point: 334.9°Cat760mmHg
• Flash Point: 164.5°C
• Appearance: /
• Density: 1.283g/cm³
• Vapor Pressure: 0.000124mmHg at 25°C
• Refractive Index: 1.557
• CAS DataBase Reference: 4-NITROPHENYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-NITROPHENYL ACRYLATE(2123-85-5)
• EPA Substance Registry System: 4-NITROPHENYL ACRYLATE(2123-85-5)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 2123-85-5(Hazardous Substances Data)

Usage

General Description

4-Nitrophenyl acrylate is a chemical compound with the molecular formula C10H7NO4. It is a nitrophenyl ester of acrylic acid and is used in the production of polymers and resins. 4-NITROPHENYL ACRYLATE is a yellow crystalline solid that is insoluble in water but soluble in organic solvents. It is primarily used as a monomer in the synthesis of specialty polymers and as a crosslinking agent in polymerization reactions. 4-Nitrophenyl acrylate is also used as a reagent in organic synthesis and as a building block in the production of various chemical compounds. Additionally, it is a potential irritant and should be handled with care in a well-ventilated area and with appropriate personal protective equipment.

InChI:InChI=1/C9H7NO4/c1-2-9(11)14-8-5-3-7(4-6-8)10(12)13/h2-6H,1H2

Upstream product

• 100-02-7 4-nitro-phenol 
• 79-10-7 acrylic acid 
• 78939-58-9 4'-nitrophenyl 3-bromopropionate 
• 814-68-6 acryloyl chloride 

Downstream Products

• 108998-69-2 p-nitrophenyl 3-(benzyloxyamino)propanoate hydrochloride 
• 114521-81-2 (1R,2S,4S)-1,4,5,6,7,7-Hexabromo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-nitro-phenyl ester 
• 117928-48-0 1,4,5,6-Tetrabromo-7,7-dimethoxy-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-nitro-phenyl ester 
• 86497-86-1 16,18-Dioxa-17-aza-tricyclo[10.6.0.0^13,17]octadecane-13,15-dicarboxylic acid 13-ethyl ester 15-(4-nitro-phenyl) ester 
• 131423-35-3 2-Methylene-pentanedioic acid bis-(4-nitro-phenyl) ester 
• 79-10-7 acrylic acid 
• 100-02-7 4-nitro-phenol 
• 17324-17-3 trans-3-methyl-1,4-diphenylazetidin-2-one 
• 94400-15-4 S-phenyl prop-2-enethioate 
• 5512-72-1 1,4-oxathiepan-7-one 

Relevant articles and documents

Triterpenoid-Based Self-Healing Supramolecular Polymer Hydrogels Formed by Host–Guest Interactions

Pentacyclic triterpenoids, a class of naturally bioactive products having multiple functional groups, unique chiral centers, rigid skeletons, and good biocompatibility, are ideal building blocks for fabricating versatile supramolecular structures. In this research, the natural pentacyclic triterpenoid glycyrrhetinic acid (GA) was used as a guest molecule for β-cyclodextrin (β-CD) to form a GA/β-CD (1:1) inclusion complex. By means of GA and β-CD pendant groups in N,N′-dimethylacrylamide copolymers, a supramolecular polymer hydrogel can be physically cross-linked by host–guest interactions between GA and β-CD moieties. Moreover, self-healing of this hydrogel was observed and confirmed by step-strain rheological measurements, whereby the maximum storage modulus occurred at a [GA]/[β-CD] molar ratio of 1:1. Additionally, these polymers displayed outstanding biocompatibility. The introduction of a natural pentacyclic triterpenoid into a hydrogel system not only provides a biocompatible guest–host complementary GA/β-CD pair, but also makes this hydrogel an attractive candidate for tissue engineering.

Unprecedented Sequence Control and Sequence-Driven Properties in a Series of AB-Alternating Copolymers Consisting Solely of Acrylamide Units

Herein, we report a method to synthesize a series of alternating copolymers that consist exclusively of acrylamide units. Crucial to realizing this polymer synthesis is the design of a divinyl monomer that contains acrylate and acrylamide moieties connected by two activated ester bonds. This design, which is based on the reactivity ratio of the embedded vinyl groups, allows a “selective” cyclopolymerization, wherein the intramolecular and intermolecular propagation are repeated alternately under dilute conditions. The addition of an amine to the resulting cyclopolymers afforded two different acryl amide units, i.e., an amine-substituted acryl amide and a 2-hydroxy-ethyl-substituted acryl amide in alternating sequence. Using this method, we could furnish ten types of alternating copolymers; some of these exhibit unique properties in solution and in the bulk, which are different from those of the corresponding random copolymers, and we attributed the differences to the alternating sequence.

Kinetic studies of conjugate addition of amines to allenic and acrylic esters and their correlation with antibacterial activities against Staphylococcus aureus

Abstract: Kinetic reactivities of various allenic and acrylic esters in conjugate addition reactions with various amines were investigated. Competition experiments showed that amines reacted selectively with allenic esters, which was also confirmed by quantitative determination of the rate constants. The antibacterial activity against Staphylococcus aureus of allenic and acrylic ester derivatives were also determined. Allenic esters were found to exhibit a higher antibacterial activity than its acrylic counterparts. A correlation between the kinetic property and the antibacterial activity suggested that a conjugate addition may involve in the antibacterial mechanism of these unsaturated esters. Graphical abstract: [Figure not available: see fulltext.].