212378-92-2

Basic information

• Product Name: (R_S)-N-benzyl-2-methylpropane-2-sulfinamide
• Synonyms: (R_S)-N-benzyl-2-methylpropane-2-sulfinamide
• CAS NO: 212378-92-2
• Molecular Weight: 211.328
• Mol File: 212378-92-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (R_S)-N-benzyl-2-methylpropane-2-sulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R_S)-N-benzyl-2-methylpropane-2-sulfinamide(212378-92-2)
• EPA Substance Registry System: (R_S)-N-benzyl-2-methylpropane-2-sulfinamide(212378-92-2)

Safety Data

• Hazardous Substances Data: 212378-92-2(Hazardous Substances Data)

Upstream product

• 67734-35-4 (R)-tert-butyl tert-butanethiosulfinate 
• 100-46-9 benzylamine 
• 196929-85-8 (R)-N-benzylidene-2-methylpropane-2-sulfinamide 
• 100-52-7 benzaldehyde 
• 100-39-0 benzyl bromide 
• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 
• 100-44-7 benzyl chloride 
• 7051-34-5 cyclopropylcarbinyl bromide 
• 5162-44-7 1-bromo-4-butene 
• 159263-57-7 (R)-3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl tert-butanesulfinate 
• 920-39-8 isopropylmagnesium bromide 
• 186249-76-3 (R,E)-2-methyl-N-(phenylmethylene)-2-propanesulfinamide 

Downstream Products

• 196929-78-9 (R)-2-methylpropane-2-sulfinamide 
• 1258840-82-2 (R)-N-benzyl-N-(bis(4-(trifluoromethyl)phenyl)phosphino)-2-methyl-2-propanesulfinamide 
• 1020731-53-6 (R)-N-benzyl-N-(di-o-tolylphosphino)-2-methyl-2-propanesulfinamide 
• 1607465-53-1 (R_S)-N-allyl-N-benzyl-2-methylpropane-2-sulfinamide 
• 1312767-75-1 (2R,2'R,5S)-2-(N-benzyl-S-tert-butylsulfinamidoyl)-3,1,2-oxazaphosphabicyclo[3.3.0]-octane 
• 1312767-75-1 (2S,2'R,5S)-2-(N-benzyl-S-tert-butylsulfinamidoyl)-3,1,2-oxazaphosphabicyclo[3.3.0]-octane 

Relevant articles and documents

Addition-Rearrangement of Ketenes with Lithium N- tert-Butanesulfinamides: Enantioselective Synthesis of α,α-Disubstituted α-Hydroxycarboxylic Acid Derivatives

Addition of the lithium salts of chiral N-substituted tert-butanesulfinamides to ketenes and subsequent silylation initiates stereoselective [2,3]-rearrangement, which affords enantioenriched α,α-disubstituted α-sulfenyloxy carboxamides through a reaction

Diastereoselective homoallylation and bis-homoallylation of N-tertbutanesulfinyl imines with organomagnesium compounds

The addition of but-3-enylmagnesium bromide and pent-4-enylmagnesium bromide to N-tert-butanesulfinyl aldimines in toluene as solvent proceeds with high diastereoselectivity to yield the corresponding products of homoallylation and bis-homoallylation, res

Potassium hydroxide-promoted selective N -monoalkylation of chiral t -butane- and p -toluenesulfinamides

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