214277-49-3

Basic information

• Product Name: (S)-1-((1S,2S,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-yl)-1-(dimethyl-phenyl-silanyl)-but-3-en-1-ol
• CAS NO: 214277-49-3
• Molecular Weight: 328.57
• Mol File: 214277-49-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-((1S,2S,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-yl)-1-(dimethyl-phenyl-silanyl)-but-3-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-((1S,2S,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-yl)-1-(dimethyl-phenyl-silanyl)-but-3-en-1-ol(214277-49-3)
• EPA Substance Registry System: (S)-1-((1S,2S,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-yl)-1-(dimethyl-phenyl-silanyl)-but-3-en-1-ol(214277-49-3)

Safety Data

• Hazardous Substances Data: 214277-49-3(Hazardous Substances Data)

Upstream product

• 7393-43-3 tetraallyl tin 
• 150614-93-0 (1S,2S,5S)-(+)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl dimethylphenylsilyl ketone 

Relevant articles and documents

Allylation reactions of acylsilanes as synthetic equivalents of aldehydes. Application of a stereocontrolled synthesis of (1S,2S,5S)-(10S)- and-(10R)-allyl myrtanol

The allylation of acylsilanes with tetraallyltin in the presence of catalytic amounts of Sc(OTf)3 proceeded smoothly to afford the silylated homoallylic alcohols in good yields. Subsequent protiodesilylation gave the formal adducts of the corre