214333-26-3

Basic information

• Product Name: [1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate
• CAS NO: 214333-26-3
• Molecular Weight: 732.892
• Mol File: 214333-26-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: [1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate(214333-26-3)
• EPA Substance Registry System: [1,4-bis(diphenylphosphino)butane-P,P'](N,N'-diethyldithiocarbamato-S,S')nickel(II) perchlorate(214333-26-3)

Safety Data

• Hazardous Substances Data: 214333-26-3(Hazardous Substances Data)

Upstream product

• 14797-73-0 perchlorate^(1-) 
• 7688-25-7 1,4-di(diphenylphosphino)-butane 

Relevant articles and documents

[1,4-bis(diphenylphosphino)butane-P,P′]-(N,N′- diethyldithiocarbamato-S,S′)-nickel(II) perchlorate

The title compound, [Ni(C5H10NS2)(C28H 28P2)]ClO4, is planar. The pairs of Ni - S [2.2089 (8) and 2.2075 (8) A] and Ni - P [2.1945(7) and 2.1932 (8)A] bond lengths are respectively equal, and the P - Ni - P angle [95.12(3)°] is large as a consequence of the flexible butyl chain between the two P atoms. The butyl chain lies on one side of the planar NiS2P2 chromophore and two of the phenyl rings are arranged laterally above the plane.