21459-27-8

Basic information

• Product Name: Bis(pentafluorophenylthio) lead(II)
• Synonyms: Bis(2,3,4,5,6-pentafluorophenylthio)lead(II);Bis(pentafluorophenylthio) lead(II)
• CAS NO: 21459-27-8
• Molecular Formula: C₁₂F₁₀PbS₂
• Molecular Weight: 605.4424
• Mol File: 21459-27-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 143.2°Cat760mmHg
• Flash Point: 51.7°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 6.77mmHg at 25°C
• CAS DataBase Reference: Bis(pentafluorophenylthio) lead(II)(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(pentafluorophenylthio) lead(II)(21459-27-8)
• EPA Substance Registry System: Bis(pentafluorophenylthio) lead(II)(21459-27-8)

Safety Data

• Hazardous Substances Data: 21459-27-8(Hazardous Substances Data)

Usage

InChI:InChI=1/2C6HF5S.Pb/c2*7-1-2(8)4(10)6(12)5(11)3(1)9;/h2*12H;/q;;+2/p-2

Upstream product

• 7439-92-1 lead 
• 771-62-0 pentafluorophenylthiol 
• 14280-50-3 lead⁽²⁺⁾ cation 
• 301-04-2 lead acetate 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 1076-44-4 pentafluorophenyl lithium 
• 392-56-3 Hexafluorobenzene 

Downstream Products

• 22577-87-3 Pentafluorphenylthio-trimethyl-silan 
• 28078-91-3 (S)-(2,3,4,5,6-pentafluorophenyl) benzenecarbothioate 
• 112515-18-1 bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)ruthenium(III) 
• 118401-42-6 dicarbonylbis(pentafluorothiophenolato)bis(diphenylmethylphosphine)ruthenium(II) 
• 1494-06-0 bis(pentafluorophenyl) disulfide 
• 10101-63-0 lead(II) iodide 
• 38086-98-5 trifluoromethyl(pentafluorophenyl)sulfane 
• 52082-75-4 bis(pentafluorophenyl)trisulfane 
• 31572-61-9 C₆F₅S^(1-)*CH₃Hg⁽¹⁺⁾ 
• 7758-95-4 lead(II) chloride 
• 31676-02-5 (SC₆F₅)2P(C₆H₅) 
• 31572-56-2 (SC₆F₅)2(C₆H₅)2Ge 
• 2034-07-3 Triphenylgermyl-maercapto-pentafluorbenzol 
• 120752-11-6 bis(diethylphenylphosphine)tris(pentafluorothiophenolato)osmium(III) 

Relevant articles and documents

Stability and trans Influence in Fluorinated Gold(I) Coordination Compounds

We examined the Au–P and Au–X chemical bonding scenario throughout the series of compounds of the general formula [AuX(LP)] wherein LP is triphenylphosphine or a fluorinated phosphine [PPhF = P(C6H5)2(C6F5) 1, P(C6H5)(C6F5)2 2 and P(C6F5)3 3] and X is chloride or a fluorinated thiolate [SRF = SCF3 a, SCH2CF3 b, SC6F5 c, SC6F4(CF3)-4 d]. We found that the increase of the fluorination degree or the replacement of Cl– by a –SRF ligand decreases the stability of the compound. Furthermore, this substitution shifts the 31P-NMR signals to low field, which indicates differences in the electronegativity of the phosphorus due to the distinct trans influences of the Cl– and –SRF species. These effects correlate with the charge of the gold atom coordinated to phosphorus. Our investigation shows the high potential of fluorination as a strategy for the modulation of the properties of gold compounds, for example in catalysis, and the applicability of quantum chemical topology studies in the explanation of these features.

DIRECT ELECTROCHEMICAL SYNTHESIS OF METAL PENTAFLUOROTHIOPHENOLATES

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