21572-32-7

Basic information

• Product Name: Ethanone, 2-chloro-1-phenyl-, oxime
• Synonyms: 2-Chlor-1-phenyl-aethanon-oxim;Ethanone,2-chloro-1-phenyl-,oxime;2-chloro-1-phenylethanone oxime
• CAS NO: 21572-32-7
• Molecular Formula: C8H8ClNO
• Molecular Weight: 169.611
• Mol File: 21572-32-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-chloro-1-phenyl-, oxime(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-chloro-1-phenyl-, oxime(21572-32-7)
• EPA Substance Registry System: Ethanone, 2-chloro-1-phenyl-, oxime(21572-32-7)

Safety Data

• Hazardous Substances Data: 21572-32-7(Hazardous Substances Data)

Upstream product

• 532-27-4 1-chloroacetophenone 
• 96-29-7 ethyl methyl ketone oxime 
• 10576-12-2 ethyl acetohydroximate 

Downstream Products

• 109261-26-9 2-chloro-1-phenyl-ethanone-((Z)-O-picryl oxime ) 
• 14181-79-4 (2-hydroxyimino-2-phenyl-ethyl)-triphenyl-phosphonium; chloride 
• 87497-91-4 9-methyl-3-phenyl-4,4a,9,9a-tetrahydro-4a,9a-butano<1,2>oxazino<6,5-b>indole 
• 87497-93-6 8-methyl-2-phenyl-3,3a,8,8a-tetrahydro-3a,8a-butanopyrrolo<2,3-b>indole 1-oxide 
• 87497-92-5 6-methyl-2,11a-diphenyl-4,5a,6,10b,11,11a-hexahydro-5a,10b-butano-3H-imidazo<1',2':2,3><1,2>oxazino<6,5-b>indole 1-oxide 
• 133350-21-7 5,6-Dihydro-6-methoxy-6-methyl-5-methylene-3-phenyl-4H-1,2-oxazine 
• 109925-93-1 5,5-Dimethyl-3-phenyl-6-trimethylsiloxy-5,6-dihydro-4H-1,2-oxazin 
• 124462-49-3 trans-5-ethyl-5,6-dihydro-3-phenyl-6-(trimethylsiloxy)-4H-1,2-oxazine 
• 124462-48-2 cis-5-ethyl-5,6-dihydro-3-phenyl-6-(trimethylsiloxy)-4H-1,2-oxazine 
• 139620-47-6 6-Ethoxy-5,5-dimethyl-3-phenyl-6-trimethylsilyloxy-5,6-dihydro-4H-1,2-oxazine 
• 139620-49-8 5,5-Diethyl-6-ethoxy-3-phenyl-6-trimethylsilyloxy-5,6-dihydro-4H-1,2-oxazine 
• 124462-54-0 trans-5,6-dihydro-3,5-diphenyl-6-(trimethylsiloxy)-4H-1,2-oxazine 
• 125173-09-3 (5R,6S)-5-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine 
• 125173-08-2 (5S,6S)-5-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine 

Relevant articles and documents

Green synthesis of 2-pyrazinones in deep eutectic solvents: From α-chloro oximes to peptidomimetic scaffolds

A novel and green synthesis of 2-pyrazinones in deep eutectic solvents (DESs) is described. Treatment of aromatic α-chloro oximes with aliphatic amines at 110 °C in choline chloride based DESs resulted in a straightforward and efficient assembly of 1,3,5-

Cobalt-catalyzed cyclization with the introduction of cyano, acyl and aminoalkyl groups

An efficient synthesis of carbo-and heterocycles using CC, CO and CN bonds under cobalt catalysis is described. The substituents on olefins are key for controlling the regio-and chemoselectivity in the initial hydrogen atom transfer step and quaternary carbons are efficiently constructed under mild conditions. Cyclopropane cleavage and tandem cyclization give highly functionalized bicyclic skeletons in a single operation.

Catalytic diastereo- and enantioselective annulations between transient nitrosoalkenes and indoles

Caught in transition: An efficient catalytic system is the key to the successful development of the first highly diastereo- and enantioselective annulation reaction between indoles and transient nitrosoalkenes. This robust reaction affords structurally unique architectures with up to three new chiral centers. The products can be readily elaborated into other indoline-based chiral heterocyclic motifs, including those of pyrrolidinoindoline alkaloids. Copyright