21577-41-3

Basic information

• Product Name: 2,4,6-tris[(Z)-2-phenylethenyl]-1,3,5-triazine
• CAS NO: 21577-41-3
• Molecular Formula: C₂₇H₂₁N₃
• Molecular Weight: 387.4757
• Mol File: 21577-41-3.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 637.1°C at 760 mmHg
• Flash Point: 279.7°C
• Density: 1.215g/cm³
• Vapor Pressure: 1.95E-15mmHg at 25°C
• Refractive Index: 1.772
• CAS DataBase Reference: 2,4,6-tris[(Z)-2-phenylethenyl]-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-tris[(Z)-2-phenylethenyl]-1,3,5-triazine(21577-41-3)
• EPA Substance Registry System: 2,4,6-tris[(Z)-2-phenylethenyl]-1,3,5-triazine(21577-41-3)

Safety Data

• Hazardous Substances Data: 21577-41-3(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 86774-68-7 1H,3H-2,4,6-trimethyl-1,3,5-triazinium triflate 
• 823-94-9 2,4,6-trimethyl-s-triazine 
• 949-42-8 2,4-bis(trichloromethyl)-6-methyl-1,3,5-triazine 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 201852-49-5 potassium (E)-trifluoro(styryl)borate 
• 1885-38-7 cinnamic nitrile 
• 333-27-7 methyl trifluoromethanesulfonate 
• 4360-47-8 cinnamonitrile 
• 1493-13-6 trifluorormethanesulfonic acid 
• 100-46-9 benzylamine 

Relevant articles and documents

Synthesis of Vinylene-Linked Covalent Organic Frameworks from Acetonitrile: Combining Cyclotrimerization and Aldol Condensation in One Pot

Combining two or more consecutive reactions in one pot is a common approach for process development, as such a method involves cheap starting materials and allows in situ generation of a reactive intermediate, to undergo further reaction, without isolation. Herein, we report the synthesis of a vinylene-linked (-CHa CH-) covalent organic framework, COF-701, directly from acetonitrile, a cheap commodity solvent, by combining/telescoping two consecutive reactions-cyclotrimerization of nitrile and subsequent aldol condensation with aldehydes-in one pot. Acetonitrile is trimerized to generate protonated 2,4,6-Trimethyl-s-Triazine tautomers in situ, which undergo Aldol condensation with 4,4′-biphenyldicarbaldehyde in one pot to form crystalline COF-701. COF-701 is obtained as a polycrystalline powder and possesses permanent microporosity and a BET surface area (SABET) of 736 m2·g-1. This strategy can be further extended to generate other porous vinylene-linked frameworks.

2D Poly(arylene vinylene) Covalent Organic Frameworks via Aldol Condensation of Trimethyltriazine

Designing structural order in electronically active organic solids remains a great challenge in the field of materials chemistry. Now, 2D poly(arylene vinylene)s prepared as highly crystalline covalent organic frameworks (COFs) by base-catalyzed aldol con

Deaminative Olefination of Methyl N-Heteroarenes by an Amine Oxidase Inspired Catalyst

We explored the bioinspired o-quinone cofactor catalyzed aerobic primary amine dehydrogenation for a cascade olefination reaction with nine different methyl N-heteroarenes, including pyrimidines, pyrazines, pyridines, quinolines, quinoxolines, benzimidazoles, benzoxazoles, benzthiazoles, and triazines. An o-quinone catalyst phd (1,10-phenanthroline-5,6-dione) combined with a Br?nsted acid catalyzed the reaction. N-Heteroaryl stilbenoids were synthesized in high yields and (E)-selectivities under mild conditions using oxygen (1 atm) as the sole oxidant without needing transition-metal salt, ligand, stoichiometric base, or oxidant.