216174-33-3

Basic information

• Product Name: methyl 2-(2-ethylidenecyclohexyl)-3-methoxypropionate
• Synonyms: methyl 2-(2-ethylidenecyclohexyl)-3-methoxypropionate
• CAS NO: 216174-33-3
• Molecular Weight: 226.316
• Mol File: 216174-33-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2-(2-ethylidenecyclohexyl)-3-methoxypropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(2-ethylidenecyclohexyl)-3-methoxypropionate(216174-33-3)
• EPA Substance Registry System: methyl 2-(2-ethylidenecyclohexyl)-3-methoxypropionate(216174-33-3)

Safety Data

• Hazardous Substances Data: 216174-33-3(Hazardous Substances Data)

Upstream product

• 932-66-1 1-cyclohexenyl methyl ketone 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 108-94-1 cyclohexanone 
• 76888-38-5 1-(1-cyclohexenyl)ethanol 
• 77197-59-2 Trimethyl-β-(methoxy) ortho propionate 
• 14315-97-0 1,1,3-trimethoxypropane 

Downstream Products

• 111615-61-3 C₁₁H₁₅⁽²⁾H₂ClO 
• 118495-56-0 2β-<1-<(Acetyloxy)methyl>ethenyl>-1α-ethenylcyclohexanol 
• 118495-57-1 2β-<1-<(Acetyloxy)methyl>ethenyl>-1β-ethenylcyclohexanol 
• 111615-44-2 2-((1S,2R)-2-Hydroxy-2-vinyl-cyclohexyl)-acrylic acid methyl ester 
• 111615-45-3 3-((1R,2S)-2-Hydroxy-2-vinyl-cyclohexyl)-but-3-en-2-one 
• 111615-48-6 2β-<1-(Bromomethyl)ethenyl>-1α-ethenylcyclohexanol 
• 111615-53-3 2β-<1-(Bromomethyl)ethenyl>-1β-ethenylcyclohexanol 
• 111615-47-5 2β-<1-(Chloromethyl)ethenyl>-1α-ethenylcyclohexanol 
• 111615-52-2 2β-<1-(Chloromethyl)ethenyl>-1β-ethenylcyclohexanol 
• 118495-55-9 2-((1S,2R)-2-Trimethylsilanyloxy-2-vinyl-cyclohexyl)-acrylic acid methyl ester 
• 111615-46-4 1α-Ethenyl-2β-<1-(hydroxymethyl)ethenyl>cyclohexanol 
• 111634-62-9 1β-Ethenyl-2β-<1-(hydroxymethyl)ethenyl>cyclohexanol 
• 118495-54-8 methyl 2-(2-ethylidenecyclohexyl)propenoate 

Relevant articles and documents

An Oxy-Cope Approach to Hydroazulenoids. Synthetic and Mechanistic Aspects of Thermal Cyclization Reactions

The synthesis and thermal properties of C5-substituted oxy-Cope substrates are reported.In the trans-divinylcyclohexanol series, halomethyl substituents provided > 80percent isolated yield of the thermodynamically less stable cis-hydroazulenone 33 from ei

Phenol catalyzed Claisen ortho ester rearrangment of allylic alcohols with trimethyl-β-(methoxy) ortho propionate

Phenol catalyzed Claisen ortho ester rearrangment of allylic alcohols with trimethyl-β-(methoxy) ortho propionate can be affected in relatively quick time and lower temperature with only 1.5 equivalents of ortho ester. The rearrangement does not experience undesirable side reactions reported earlier in literature [3].