2168-85-6

Basic information

• Product Name: methyl phenyldithioacetate
• Synonyms: methyl phenyldithioacetate
• CAS NO: 2168-85-6
• Molecular Weight: 182.31
• Mol File: 2168-85-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: methyl phenyldithioacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl phenyldithioacetate(2168-85-6)
• EPA Substance Registry System: methyl phenyldithioacetate(2168-85-6)

Safety Data

• Hazardous Substances Data: 2168-85-6(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 74-88-4 methyl iodide 
• 74-93-1 methylthiol 
• 83893-97-4 (thiocyanatoethynyl)benzene 
• 68542-14-3 2-Phenyl-1-methylthio-1-(acetoxymethylthio)-ethylene 
• 2314-48-9 (S,S)-dimethyl trithiocarbonate 
• 108-88-3 toluene 
• 756-80-9 O,O-dimethyl phosphorodithioic acid 
• 103-80-0 phenylacetyl chloride 
• 82737-61-9 2,4-bis(methylthio)-1,3-dithia-2,4-diphosphetane-2,4-disulfide 
• 103-82-2 phenylacetic acid 
• 141983-09-7 1-<2-(tert-butyldithio)-2-(methylthio)ethenyl>benzene 
• 100-52-7 benzaldehyde 
• 141982-88-9 diisopropyl <(methyldithio)(methylthio)methyl>phosphonate 

Downstream Products

• 15985-67-8 N-phenylthioacetyl-valine 
• 101956-05-2 N-phenylthioacetyl-DL-isoleucine 
• 93311-16-1 N-phenethyl-2-phenylethanethioamide 
• 22871-49-4 N-butyl-2-phenylethanethioamide 
• 59718-99-9 2-benzyl-6-phenyl-1⁽³⁾H-thieno[3,4-d]imidazole-4-carboxylic acid methyl ester 
• 63820-33-7 N,N'-Dimethyl-N,N'-bis-(phenylthioacetyl)-propan-1,3-diamin 
• 90032-93-2 (E)-6-Methylsulfanylthiocarbonyl-6-phenyl-hex-3-enoic acid 
• 13846-65-6 3-Benzyl-2-cyano-3-methylthioacrylonitrile 
• 5841-50-9 5-methylsulfanyl-4-phenyl-[1,2]dithiole-3-thione 
• 14063-69-5 β,β-bis(methylthio)styrene 
• 45953-08-0 (phenyl)thioacetylhydrazine 
• 63820-32-6 N,N'-Dimethyl-N,N'-bis-(phenylthioacetyl)-aethylendiamin 
• 6079-56-7 (2-(methylsulfonyl)ethyl)benzene 
• 55008-10-1 bis(1-methylthio-2-phenylvinyl)disulfide 

Relevant articles and documents

Synthesis of chiral sulfines by oxidation of dithio esters

The synthesis of sulfines (thione oxides) (2, 10 and 17) derived from three chiral dithio esters (1, 8 and 16) bearing a hydrogen at the α-carbon atom is described.The sulfine bearing an amido group at C-α (2), does not racemize and proved to be stable ov

THE REACTION OF CARBOXYLIC ACID CHLORIDES WITH O,O-DIALKYLDITHIOPHOSPHORIC ACIDS

At high temperature (130 deg C), carboxylic acid chlorides react with O,O-dialkyldithiophosphoric acids (RO)2P(=S)(SH), Ia-c to give the corresponding dithiester RC(=S)(SR) II in varying yields, while benzoyl chloride reacts with compounds Ia, b at 20 deg C to give the corresponding S-benzoyl-O,O-dialkyldithiophosphate (RO)2P(=S) IIIa, b.Mechanistic consideration on the formation of the products are discussed.Key words: Carboxylic acid chlorides; O,O-dialkyldithiophosphoric acids, and S-benzoyl-O,O-dialkyldithiophosphates.

SYNTHESE DIRECTE DE DITHIOESTERS A PARTIR DES ACIDES CARBOXYLIQUES

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