21813-34-3

Basic information

• Product Name: 1H-Stannole, 1,1,2,3,4,5-hexaphenyl-
• CAS NO: 21813-34-3
• Molecular Formula: C40H30Sn
• Molecular Weight: 629.388
• Mol File: 21813-34-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1H-Stannole, 1,1,2,3,4,5-hexaphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Stannole, 1,1,2,3,4,5-hexaphenyl-(21813-34-3)
• EPA Substance Registry System: 1H-Stannole, 1,1,2,3,4,5-hexaphenyl-(21813-34-3)

Safety Data

• Hazardous Substances Data: 21813-34-3(Hazardous Substances Data)

Upstream product

• 77904-06-4 1-bromo-1,2,3,4-tetraphenyl-4-(tribromostannyl)-1,3-butadiene 
• 591-51-5 phenyllithium 
• 1135-99-5 diphenyltin(IV) dichloride 
• 21289-08-7 (E,E)-(1,2,3,4-tetramethyl-1,3-butadien-1,4-ylidene)-dilithium 
• 21289-08-7 1,4-dilithio-1,2,3,4-tetraphenylbutadiene 

Downstream Products

• 1135-99-5 diphenyltin(IV) dichloride 
• 77904-13-3 1,1-diiodo-2,3,4,5-tetraphenylstannole 
• 55690-98-7 1,1-dibromo-2,3,4,5-tetraphenylstannole 
• 954386-23-3 1-lithio-2,3,4,5-tetraphenyl-1-(triphenylstannyl)stannole 
• 954386-25-5 2,3,4,5-tetraphenyl-1,1-bis(triphenylstannyl)stannole 
• 954386-22-2 1-lithio-2,3,4,5-tetraphenyl-1-(triisopropylsilyl)stannole 
• 954386-20-0 1-[2,6-bis(2,4,6-trimethylphenyl)phenyl]-1-lithio-2,3,4,5-tetraphenylstannole 
• 954386-21-1 1-[2,6-bis(2,4,6-triisopropylphenyl)phenyl]-1-lithio-2,3,4,5-tetraphenylstannole 
• 954386-18-6 1-methyl-2,3,4,5-tetraphenyl-1-(2,4,6-triisopropylphenyl)stannole 
• 954386-24-4 1-methyl-2,3,4,5-tetraphenyl-1-(triphenylstannyl)stannole 
• 625111-00-4 bi(1-tert-butyl-2,3,4,5-tetraphenyl-1-stanna-cyclopentadienyl) 
• 625110-98-7 1-tert-butyl-1-methyl-2,3,4,5-tetraphenylstannole 
• 20195-60-2 1,1-dimethyl-2,3,4,5-tetraphenylstannole 

Relevant articles and documents

Synthesis and structures of bi(1,1-stannole)s

The synthesis and structures of bi(1,1-stannole)s are described. Treatment of 1-bromo-4-(dibromophenylstannyl)-1,3-butadiene with tert-butyllithium gives the bi(1,1-stannole) having a phenyl group on each tin atom, whereas treatment of 1-bromo-4-(tribromostannyl)-1,3-butadiene with phenyl- or bulky alkyllithiums gives the bi(1,1-stannole) having a phenyl or an alkyl group on each tin atom. The X-ray analysis of the tert-butyl-substituted bi(1,1-stannole) is also described. All bi(1,1-stannole)s display two shoulder absorption bands due to π-π* and σ-π* transitions. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.

Synthesis of Tetraphenylstannacyclopentadienes (Stannoles). 1. Alkylation of 1,1-Dihalostannoles Leading to Lithium 1,1-Bis(η1-cyclopentadienyl)-1-halo-2,3,4,5-tetraphenylstannole, an - Anion with Pseudorotating Axial- and Equ

1,1-Dibromo- and 1,1-diiodo-2,3,4,5-tetraphenylstannacyclopentadienes (dibromo- and diiodostannoles) formed from controlled phenyltin cleavage of hexaphenylstannole by elemental bromine and iodine, respectively, undergo conventional alkylation by methylli