219601-21-5

Basic information

• Product Name: 1-hexenyl phenyl sulfoxide
• Synonyms: 1-hexenyl phenyl sulfoxide
• CAS NO: 219601-21-5
• Molecular Weight: 208.324
• Mol File: 219601-21-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-hexenyl phenyl sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-hexenyl phenyl sulfoxide(219601-21-5)
• EPA Substance Registry System: 1-hexenyl phenyl sulfoxide(219601-21-5)

Safety Data

• Hazardous Substances Data: 219601-21-5(Hazardous Substances Data)

Upstream product

• 110-62-3 pentanal 
• 442159-98-0 1-(phenylsulfinyl)-2-hexanol 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 442159-99-1 2-mesyloxy-1-(phenylsulfinyl)hexane 
• 50746-65-1 Diethyl (phenylsulfinyl)methylphosphonate 

Downstream Products

• 219601-28-2 (2-Benzenesulfinylmethyl-1,1-difluoro-hexyl)-phosphonic acid diethyl ester 
• 442160-27-2 3-mesyloxy-1-phenyl-4-(phenylsulfinyl)-4-nonene 
• 442160-40-9 3-acetoxy-1-phenyl-4-(phenylsulfinyl)-4-nonen-1-yne 
• 442160-04-5 (1E)-3-acetoxy-1-phenyl-4-(phenylsulfinyl)-1,4-nonadiene 
• 67647-96-5 nona-3,4-dien-1-ylbenzene 
• 442160-39-6 1-phenyl-4-(phenylsulfinyl)-4-nonen-1-yn-3-ol 
• 442160-26-1 1-phenyl-4-(phenylsulfinyl)-4-nonen-3-ol 
• 442160-03-4 (1E)-1-phenyl-4-(phenylsulfinyl)-1,4-nonadien-3-ol 

Relevant articles and documents

A new method for synthesis of allenes, including an optically active form, from aldehydes and alkenyl aryl sulfoxides by sulfoxide-metal exchange as the key reaction and an application to a total synthesis of male bean weevil sex attractant

The sulfoxide-metal exchange reaction of β-acetoxy sulfoxides or β-mesyloxy sulfoxides, which were derived from alkenyl aryl sulfoxides and aldehydes in two steps, with a Grignard reagent or alkyllithium at low temperature gave allenes in good yields. Optically active allenes were synthesized starting from optically active 2-substituted ethenyl p-tolyl sulfoxides. A synthesis of (-)-methyl (E)-2,4,5-tetradecatrienoate, a male bean weevil sex attractant, was realized by this method.