219843-48-8

Basic information

• Product Name: 2-(biphenyl-2-yl)pyridine
• Synonyms: 2-(biphenyl-2-yl)pyridine
• CAS NO: 219843-48-8
• Molecular Weight: 231.297
• Mol File: 219843-48-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-(biphenyl-2-yl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(biphenyl-2-yl)pyridine(219843-48-8)
• EPA Substance Registry System: 2-(biphenyl-2-yl)pyridine(219843-48-8)

Safety Data

• Hazardous Substances Data: 219843-48-8(Hazardous Substances Data)

Upstream product

• 1221640-33-0 N,N-dimethyl-2-(pyridin-2-yl)aniline 
• 201230-82-2 carbon monoxide 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 198478-48-7 (phenyl)(2-(pyridin-2-yl)phenyl)methanone 
• 1008-89-5 2-phenylpyridine 
• 1746-13-0 allyl phenyl ether 
• 100-58-3 phenylmagnesium bromide 
• 99-91-2 para-chloroacetophenone 
• 108-90-7 chlorobenzene 

Relevant articles and documents

Ruthenium-Catalyzed Carbonylative Coupling of Anilines with Organoboranes by the Cleavage of Neutral Aryl C-N Bond

Herein, we report the first ruthenium-catalyzed Suzuki-type carbonylative reaction of electronically neutral anilines via C(aryl)-N bond cleavage. Without any ligand and base, diaryl ketones can be obtained in moderate to high yields by using Ru3/su

Ortho-allylation of 1-arylpyrazoles with allyl phenyl ether via iron-catalyzed C-H bond activation under mild conditions

An iron salt and a bipyridine-type ligand catalyze the ortho-allylation of 1-arylpyrazoles and congeners with allyl phenyl ether under mild conditions (0 °C). The ligand, an organozinc base, and the nature of the allylating reagent are crucial for the success of this reaction. Under these conditions, a competitive phenylation reaction is largely retarded, and cross-coupling of the organozinc with the allyl electrophile is minimized. The reaction may proceed via iron-catalyzed ortho C-H activation to form a metallic intermediate, which then reacts with the allyl ether in a γ selective fashion.

RuCi3 xH2O-catalyzed direct arylation of arenes with aryl chlorides in the presence of triphenylphosphine

A study was conducted to demonstrate the RuCl3·xH 2O catalytic system for direct arylation of arenes with aryl chlorides. The phenylation of benzo[h]quinoline with chlorobenzene was investigated under preliminary studies. The reaction of benzo[h]quinoline and chlorobenzene N-methyl-2-pyrrolidone (NMP) formed Ph as the only product in 86-93% yields at 120-130 8C in the presence of K2CO3 using 5 mol% RuCl3·xH2O and 10 mol% PPh3. It was observed that the presence of an excess of ligand did not affect formation of Ph, while sub-stoichiometric ligand amounts led to a reduced conversion for benzo[h]quinoline. The arylation and benzylation of benzo[h]quinoline with various aryl chlorides was also investigated under the study.