21990-63-6Relevant articles and documents
Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents
Nishimura, Kazutoshi,Hirano, Koji,Miura, Masahiro
supporting information, p. 3185 - 3189 (2020/04/21)
We have developed a new strategy for the generation of phosphenium dication equivalents from readily available phosphinic acids and Tf2O. The in situ-generated dication equivalents can be readily coupled with simple (hetero)biaryls to form the corresponding dibenzophospholes directly. This protocol can also be applied to the concise synthesis of six- A nd seven-membered phosphacycles as well as the largely ?-extended heteroacene derivatives, which are of great interest in the field of organic functional materials.