22034-19-1Relevant articles and documents
Tuning the Selectivity of AuPd Nanoalloys towards Selective Dehydrogenative Alkyne Silylation
Wissing, Maren,Studer, Armido
, p. 5870 - 5874 (2019)
The cross-dehydrogenative coupling of terminal alkynes and hydrosilanes catalyzed by AuPd nanoalloys is described. Metal nanoparticles are readily prepared in 15 minutes from commercially available and cheap starting materials by using a photochemical app
Silyl-pyridine-amine pincer-ligated iridium complexes for catalytic silane deuteration: Via room temperature C-D bond activation of benzene- d 6
Komuro, Takashi,Osawa, Tomohiro,Suzuki, Ryuju,Mochizuki, Daiki,Higashi, Hironori,Tobita, Hiromi
, p. 957 - 960 (2019)
Iridium-hydrido complexes bearing a hemilabile silyl-pyridine-amine pincer ligand were synthesised. They were found to catalyse Si-H deuteration of trialkylsilanes with excess benzene-d6 in 99-94% conversion at room temperature through C-D bond
A General Rhodium Catalyst for the Deuteration of Boranes and Hydrides of the Group 14 Elements
Esteruelas, Miguel A.,Martínez, Antonio,Oliván, Montserrat,Vélez, Andrea
, p. 15693 - 15698 (2020/12/02)
Pinacolborane, catecholborane, triethylsilane, triphenylsilane, dimethylphenylsilane, 1,1,1,3,5,5,5-heptamethyltrisiloxane, triethylgermane, triphenylgermane, and triphenylstannane deuterated at the heteroatom position have been catalytically prepared in
