220592-43-8

Basic information

• Product Name: Bi(SOCC₆H₄CH₃)3
• CAS NO: 220592-43-8
• Molecular Weight: 662.607
• Mol File: 220592-43-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bi(SOCC₆H₄CH₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: Bi(SOCC₆H₄CH₃)3(220592-43-8)
• EPA Substance Registry System: Bi(SOCC₆H₄CH₃)3(220592-43-8)

Safety Data

• Hazardous Substances Data: 220592-43-8(Hazardous Substances Data)

Upstream product

• 50684-47-4 2-methyl-thiobenzoic acid 
• 1304-76-3 bismuth(III) oxide 

Relevant articles and documents

Arsenic(III), Antimony(III) and Bismuth(III) Thiobenzoates: Crystal and Molecular Structures of M(SOCR)3 and PhSb(SOCPh)2

Tris-thiobenzoates of arsenic, antimony and bismuth, M(SOCR)3 have been obtained from their oxides and characterized. In the X-ray crystal structure determinations of these, the group 15 atom and the three covalently bonded sulfur atoms are found to constitute a trigonal pyramid, the central atoms lie at a C3 axis. In the bismuth complex the thiobenzoate ligand tends to chelate. However, three comparatively short intermolecular M-S interactions are significant features for these molecules resulting in slacking of trigonal prisms providing an essentially six coordinate environment around arsenic and antimony and a nine-coordinate one for bismuth. The structure of PhSb(SOCPh)2 can be considered to be distorted trigonal bipyramidal.