2216-38-8

Basic information

• Product Name: TRANS-2-NONENE
• Synonyms: non-2-ene;TRANS-2-NONENE;2-NONENE;2-Nonene (cis- and trans - mixture);2-NONENE(CIS- AND TRANS- MIXTURE) 95+%;2-Nonene (cis- and trans- mixture)
• CAS NO: 2216-38-8
• Molecular Formula: C₉H₁₈
• Molecular Weight: 126.24
• Mol File: 2216-38-8.mol
• Article Data: 8

Chemical Properties

• Melting Point: -89.14°C (estimate)
• Boiling Point: 144-145 °C(lit.)
• Flash Point: 90 °F
• Appearance: /
• Density: 0.734 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.42(lit.)
• CAS DataBase Reference: TRANS-2-NONENE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-2-NONENE(2216-38-8)
• EPA Substance Registry System: TRANS-2-NONENE(2216-38-8)

Safety Data

• Statements: 10
• Safety Statements: 16-29-33
• RIDADR: UN 3295 3/PG 3
• WGK Germany: 3
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 2216-38-8(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 201230-82-2 carbon monoxide 
• 617-86-7 triethylsilane 
• 83511-78-8 trimethyl(non-1-en-2-yloxy)silane 
• 334-48-5 1-decanoic acid 
• 111-66-0 oct-1-ene 
• 124-11-8 non-1-ene 
• 107-31-3 Methyl formate 
• 124-40-3 dimethyl amine 
• 623-93-8 5-nonanol 
• 22433-33-6 Nona-1,2-dien 

Downstream Products

• 112-31-2 caprinaldehyde 
• 56820-01-0 2-hexyl-3-methyl-oxirane 
• 111-71-7 heptanal 
• 24424-67-7 2-methyl-1-nonanal 
• 37596-38-6 2-ethyl-octanal 
• 76058-49-6 2-(n-propyl)-heptanal 

Relevant articles and documents

Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes

A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh3) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh3 system.

Effect of the presence of ionic liquid during the NiMoS bulk preparation in the transformation of decanoic acid

The impact of the presence and amount of [BMIM][NTf2] ionic liquid during the preparation of bulk NiMoS catalysts was investigated. It was clearly shown that these factors have a strong influence on both the morphology and specific surface area of the obtained NiMoS samples. Most interestingly the catalytic activity for the transformation of decanoic acid increased up to three times when IL was present during synthesis. In the same time, a greater selectivity towards hydrocarbons was observed. On the whole a clear relationship between catalytic activity, selectivity and NiMoS morphology was demonstrated. Consequently, it is possible to modify the morphology of the materials and impact the catalytic properties by changing the synthesis conditions.

Methylformate as replacement of syngas in one-pot catalytic synthesis of amines from olefins

A new general approach for the one-pot hydroaminomethylation of olefins using methylformate as formylating agent instead of synthesis gas (syngas) has been proposed. Herein we report that a Ru-Rh catalytic system demonstrates high activity in a tandem conversion of a series of n-alkenes into amines using methylformate with yields 58-92% (6 h). The selectivity for the normal amine reached 96% with catalysis by the Ru carbonyl complex Ru3(CO) 12, with an overall yield of 55% with respect to amine in this instance. The addition of the Rh complex to Ru catalytic system, sharply increased the hydroaminomethylation rate of both the terminal and internal alkenes and increased the yield of amines to 82-93% (6-12 h). The Royal Society of Chemistry.