221677-66-3

Basic information

• Product Name: cepaciamide B p-methoxybenzyl ether
• Synonyms: cepaciamide B p-methoxybenzyl ether
• CAS NO: 221677-66-3
• Molecular Weight: 769.162
• Mol File: 221677-66-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cepaciamide B p-methoxybenzyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: cepaciamide B p-methoxybenzyl ether(221677-66-3)
• EPA Substance Registry System: cepaciamide B p-methoxybenzyl ether(221677-66-3)

Safety Data

• Hazardous Substances Data: 221677-66-3(Hazardous Substances Data)

Upstream product

• 231299-15-3 tert-butyl-[2-(4-methoxy-benzyloxy)-10-(tetrahydro-pyran-2-yloxy)-decyloxy]-diphenyl-silane 
• 231299-16-4 (S)-10-(tert-butyldiphenylsilyloxy)-9-(p-methoxybenzyloxy)-1-decanol 
• 221677-67-4 (-)-(S)-4-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)butyl 4-methylbenzenesulfonate 
• 221677-53-8 (S)-10-(tert-butyldiphenylsilyloxy)-9-(p-methoxybenzyloxy)-1-decyl bromide 
• 231299-10-8 (3R,3'S)-3-(3'-acetoxyhexadecanoylamino)-2-piperidinone 
• 221677-54-9 (S)-2-(p-methoxybenzyloxy)-11-octadecyn-1-ol 
• 221677-63-0 (2S,11Z)-2-(p-methoxybenzyloxy)-11-octadecen-1-ol 
• 231299-09-5 tert-butyl (2S,3S)-3-acetoxy-2-chlorohexadecanoate 
• 221677-48-1 (3S)-4-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-3-[(4-methoxybenzyl)oxy]butan-1-ol 
• 231299-11-9 (2S,4S)-tert-butyl-[2-(4-methoxy-phenyl)-[1,3]dioxan-4-ylmethoxy]-diphenyl-silane 
• 221874-62-0 tert-butyl (S)-3-acetoxyhexadecanoate 
• 122767-78-6 (S)-(+)-3-acetoxyhexadecanoic acid 
• 103708-37-8 (2S,4S)-4-hydroxymethyl-2-(p-methoxymethyl)-1,3-dioxane 
• 221677-62-9 (2S,11Z)-2-(p-methoxybenzyloxy)-11-octadecenoic acid 

Relevant articles and documents

Study on fungitoxic 3-amino-2-piperidinone-containing lipids: Total syntheses of cepaciamides A and B

Total syntheses of cepaciamides A and B were accomplished. In the preparation of two fatty acid segments, (S)-malic acid was used as a chiral source to introduce (2S)-configuration. A known chiral cyclopropane derivative was introduced in the segment of cepaciamide A. The formation of (Z)-olefin in the segment of cepaciamide B was achieved by means of partial reduction of the acetylenic bond. Estexification between fatty acid segments and amide segment with DCC/DMAP and subsequent oxidative deprotection of the MPM group with CAN gave cepaciamides.