2217-81-4

Basic information

• Product Name: DIPHENYLSELENIUM DICHLORIDE
• Synonyms: SELENIUM DIPHENYL DICHLORIDE;DIPHENYLSELENIUM DICHLORIDE;Diphenylselenium dichloride,97%
• CAS NO: 2217-81-4
• Molecular Formula: C₁₂H₁₀Cl₂Se
• Molecular Weight: 304.07
• Mol File: 2217-81-4.mol
• Article Data: 1

Chemical Properties

• Melting Point: 178-183 °C
• Appearance: /solid
• CAS DataBase Reference: DIPHENYLSELENIUM DICHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIPHENYLSELENIUM DICHLORIDE(2217-81-4)
• EPA Substance Registry System: DIPHENYLSELENIUM DICHLORIDE(2217-81-4)

Safety Data

• Hazard Codes: N-T
• Statements: 50/53-33-23/25
• Safety Statements: 61-60-45-28A-20/21
• RIDADR: 3283
• Hazardous Substances Data: 2217-81-4(Hazardous Substances Data)

Usage

Chemical Properties

PALE YELLOW CRYSTALLINE POWDER

Upstream product

• 7446-70-0 aluminium trichloride 
• 7446-08-4 selenium(IV) oxide 
• 71-43-2 benzene 
• 7647-01-0 hydrogenchloride 
• 10504-99-1 diphenyl selenone 
• 7304-91-8 diphenylselenoxide 
• 1132-39-4 diphenylselenide 
• 7697-37-2 nitric acid 
• 1666-13-3 diphenyl diselenide 
• 4190-46-9 diphenylselenium dibromide 
• 127-63-9 diphenyl sulphone 
• 108-86-1 bromobenzene 

Downstream Products

• 1132-39-4 diphenylselenide 
• 58235-79-3 bis(4-chlorophenyl)selenide 
• 7304-91-8 diphenylselenoxide 
• 6158-73-2 triphenylselenonium chloride 
• 130286-01-0 C₁₆H₁₄F₆O₂Se 
• 56593-11-4 2-(Diphenyl-λ⁴-selanylidene)-malononitrile 
• 52867-19-3 diphenyl-N-(p-toluenesulfonyl)selenimide 
• 52867-18-2 N-phenylsulphonyl-Se,Se-diphenylselenimide 
• 116161-52-5 N-(Benzylsulfonyl)diphenylselenimide 
• 80014-70-6 N-(Trichloroacetyl)diphenylselenimide 
• 123316-11-0 Diphenylhydroxy(N-trichloroacetylamino)selenane 
• 154108-98-2 (CH₃COOHgC₆H₄)2SeCl₂ 
• 154108-99-3 (CF₃COOHgC₆H₄)2SeCl₂ 

Relevant articles and documents

Organoselenium-catalyzed vicinal dichlorination of unsaturated phosphonates

Diphenyl diselenide (PhSeSePh) was effective as a pre-catalyst for the vicinal dichlorination of α,β-unsaturated phosphonates with sulfuryl chloride. The reaction conditions were mild and the desired products were formed in up to 93% yield and moderate diastereoselectivity (10:1). The important diphenylselenium dichloride intermediate was obtained and characterized by X-ray crystallography.