22259-85-4

Basic information

• Product Name: 2-(benzenesulfonyloxy)-2-phenyl-acetonitrile
• Synonyms: 2-(benzenesulfonyloxy)-2-phenyl-acetonitrile
• CAS NO: 22259-85-4
• Molecular Formula: C₁₄H₁₁NO₃S
• Molecular Weight: 273.30624
• Mol File: 22259-85-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 451.2 °C at 760 mmHg
• Flash Point: 226.7 °C
• Appearance: /
• Density: 1.308 g/cm³
• Vapor Pressure: 2.49E-08mmHg at 25°C
• Refractive Index: 1.597
• CAS DataBase Reference: 2-(benzenesulfonyloxy)-2-phenyl-acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzenesulfonyloxy)-2-phenyl-acetonitrile(22259-85-4)
• EPA Substance Registry System: 2-(benzenesulfonyloxy)-2-phenyl-acetonitrile(22259-85-4)

Safety Data

• Hazardous Substances Data: 22259-85-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 4517, 1951 DOI: 10.1021/ja01154a005

InChI:InChI=1/C14H11NO3S/c15-11-14(12-7-3-1-4-8-12)18-19(16,17)13-9-5-2-6-10-13/h1-10,14H

Upstream product

• 151-50-8 potassium cyanide 
• 100-52-7 benzaldehyde 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 490-55-1 amiphenazole 
• 93871-46-6 3-allyl-4-amino-5-phenyl-3H-thiazol-2-ylideneamine 
• 60126-70-7 4-amino-3-ethyl-2-methylsulfanyl-5-phenyl-thiazolium; benzenesulfonate 
• 50566-90-0 4-nitro-benzoic acid N'-(4-amino-5-phenyl-thiazol-2-yl)-hydrazide 
• 47298-21-5 3-methyl-benzoic acid N'-(4-amino-5-phenyl-thiazol-2-yl)-hydrazide 
• 47298-23-7 4-methyl-benzoic acid N'-(4-amino-5-phenyl-thiazol-2-yl)-hydrazide 
• 47298-22-6 3-chloro-benzoic acid N'-(4-amino-5-phenyl-thiazol-2-yl)-hydrazide 
• 47298-24-8 4-chloro-benzoic acid N'-(4-amino-5-phenyl-thiazol-2-yl)-hydrazide 
• 47147-98-8 2-[N'-(2-chloro-phenyl)-hydrazino]-5-phenyl-thiazol-4-ylamine 
• 47154-64-3 5-phenyl-2-(N'-m-tolyl-hydrazino)-thiazol-4-ylamine 
• 47154-66-5 5-phenyl-2-(N'-p-tolyl-hydrazino)-thiazol-4-ylamine 
• 82646-26-2 4-amino-2-methylthio-5-phenylthiazolium benzenesulfonate 
• 104194-61-8 Benzenesulfonate₃-(2-carboxy-ethyl)-6-methylsulfanyl-2-oxo-8-phenyl-1,2-dihydro-thiazolo[3,4-b][1,2,4]triazin-5-ylium; 
• 104194-59-4 Benzenesulfonate₃-methyl-6-methylsulfanyl-2-oxo-8-phenyl-1,2-dihydro-thiazolo[3,4-b][1,2,4]triazin-5-ylium; 

Relevant articles and documents

Substituent Effects on the CC-Bond Strength, 5. Kinetics and Thermochemistry of the Homolytic Dissociation of meso- and D,L-2,3-Dimethoxy-2,3-diphenylsuccinonitrile

The differences in enthalpy and entropy between meso- and DL-2,3-dimethoxy-2,3-diphenylsuccinonitrile (2) were deduced from the equilibrium constants of their interconversion at elevated temperatures via reversible dissociation into α-cyano-α-methoxybenzy