222844-98-6

Basic information

• Product Name: 3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose
• Synonyms: 3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose
• CAS NO: 222844-98-6
• Molecular Weight: 430.498
• Mol File: 222844-98-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose(222844-98-6)
• EPA Substance Registry System: 3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose(222844-98-6)

Safety Data

• Hazardous Substances Data: 222844-98-6(Hazardous Substances Data)

Upstream product

• 1450734-54-9 4-methoxybenzyl N-phenyl-2,2,2-trifluoroacetimidate 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 105-13-5 4-Methoxybenzyl alcohol 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 37073-70-4 1-(6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-trityloxyethanol 
• 100-39-0 benzyl bromide 
• 1380315-47-8 3-O-benzyl-5-O-(4-methoxybenzyl)-6-O-triphenylmethyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 1380315-48-9 3-O-benzyl-6-O-(2-bromomethylbenzyl)-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-49-0 6-O-(2-azidomethylbenzyl)-3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-50-3 C₆₈H₇₃N₃O₁₂S 
• 1380315-51-4 C₆₀H₆₅N₃O₁₁S 
• 1380315-53-6 6-O-(3-azidomethylbenzyl)-3-O-benzyl-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 1380315-54-7 C₆₈H₇₃N₃O₁₂S 
• 1380315-55-8 C₆₀H₆₅N₃O₁₁S 
• 1380315-52-5 3-O-benzyl-6-O-(3-bromomethylbenzyl)-5-O-(4-methoxybenzyl)-1,2-O-isopropylidene-α-D-glucofuranose 
• 198995-06-1 (S)-2-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(4-methoxy-benzyloxy)-ethanethiol 
• 83318-92-7 ethyl p-methoxybenzyl sulfide 

Relevant articles and documents

P-Methoxybenzyl-N-phenyl-2,2,2-trifluoroacetimidate: A versatile reagent for mild acid catalyzed etherification

PMB-NPTFA 1a is a new month bench stable and powerful reagent for the formation of PMB ethers. Several alcohols were protected in high yields and short reaction times, using low reagent loading and small catalytic amounts of Bi(OTf)3. The mild

Regioselective deprotection of p-methoxybenzyl ethers of furanose derivatives

Reaction of per-p-methoxybenzylated hexofuranoses and pentofuranoses with either a catalytic amount of tin chloride dihydrate (SnCl2·2H2O) or 0.5-10% solution of trifluoroaoetic acid in dichloromethane afforded regioselectively the corresponding monosaccharide derivatives having a single free hydroxyl group at C(5) in good yields.