223565-85-3

Basic information

• Product Name: Cl(C₆H₅)2Sn(Si(CH₃)2)6Sn(C₆H₅)2Cl
• Synonyms: Cl(C₆H₅)2Sn(Si(CH₃)2)6Sn(C₆H₅)2Cl
• CAS NO: 223565-85-3
• Molecular Weight: 965.68
• Mol File: 223565-85-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cl(C₆H₅)2Sn(Si(CH₃)2)6Sn(C₆H₅)2Cl(CAS DataBase Reference)
• NIST Chemistry Reference: Cl(C₆H₅)2Sn(Si(CH₃)2)6Sn(C₆H₅)2Cl(223565-85-3)
• EPA Substance Registry System: Cl(C₆H₅)2Sn(Si(CH₃)2)6Sn(C₆H₅)2Cl(223565-85-3)

Safety Data

• Hazardous Substances Data: 223565-85-3(Hazardous Substances Data)

Upstream product

• 812-54-4 1,6-dichlorododecamethylhexasilane 

Relevant articles and documents

Synthesis and reactivity of stannyloligosilanes, I. Stannyloligosilane chains containing SiMe2 moieties

Stannyloligosilanes 1 and 2 with terminal organotin groups are available by reacting alkali metal tri-or diorganostannides with α,ω-dichloro-or difluorosilanes, or by treatment of organochlorostannanes with α,ω-difluorosilanes in the presence of magnesium. Attempts to functionalize the triorganotin derivatives 2 by halogenation reagents did not result in the halogen compounds 5; instead cleavage of silicon-tin bonds is observed. In contrast, reactions of the hydridotin derivatives 1 with CHX3 (X = Cl, Br) lead to the quantitative formation of the bis(chloro-or bromostannyl)oligosilanes 5. All compounds were characterized by NMR, IR, MS and elemental analysis. In addition, the triorganotin compound 2i and the hydridotin species 1b have been characterized by X-ray crystallography.