223616-27-1

Basic information

• Product Name: ((η(4)-C6H8)Fe(CO)2)2(μ-Ph2P(CH2)6PPh2)
• CAS NO: 223616-27-1
• Molecular Weight: 838.526
• Mol File: 223616-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((η(4)-C6H8)Fe(CO)2)2(μ-Ph2P(CH2)6PPh2)(CAS DataBase Reference)
• NIST Chemistry Reference: ((η(4)-C6H8)Fe(CO)2)2(μ-Ph2P(CH2)6PPh2)(223616-27-1)
• EPA Substance Registry System: ((η(4)-C6H8)Fe(CO)2)2(μ-Ph2P(CH2)6PPh2)(223616-27-1)

Safety Data

• Hazardous Substances Data: 223616-27-1(Hazardous Substances Data)

Upstream product

• 12152-72-6 (cyclohexa-1,3-diene)iron tricarbonyl 
• 19845-69-3 1,6-bis(diphenylphosphino)hexane 

Relevant articles and documents

Synthesis of dibridged diphosphine metal carbonyl complexes and related phosphine transfer reactions

A series of dibridged diphosphine metal complexes of general formula [5,5′-dppx1-{(η4-C6H7)Fe(CO)2}2-(μ-dppx2)][BF4]2 (x1, x2=p, p (IX); x1, x2=b, b (X); x1, x2=n, n (XI); x1, x2=h, h (XII); x1=p, x2=b (XIII); x1=b, x2=n (XIV); x1=n, x2=h (XV)) containing both metal-metal and ring-ring diphosphine bridges are reported. In the course of the synthetic studies, phosphine transfer reactions (both mono and diphosphine) were observed between a metal bonded phosphine and a sufficiently electrophilic metal carbonyl cation. Phosphine transfer also occurs when normal hydride abstraction reactions are attempted with only stoichiometric amounts of [Ph3C][BF4].