22627-45-8

Basic information

• Product Name: 2-Cyclohexen-1-one, 3-(3-butenyl)-
• CAS NO: 22627-45-8
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Mol File: 22627-45-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 3-(3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 3-(3-butenyl)-(22627-45-8)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 3-(3-butenyl)-(22627-45-8)

Safety Data

• Hazardous Substances Data: 22627-45-8(Hazardous Substances Data)

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 56671-81-9 3-bromo-2-cyclohexen-1-one 
• 917-57-7 vinyllithium 
• 7103-09-5 4-but-1-enylmagnesium bromide 
• 145102-57-4 ((3-(but-3-en-1-yl)cyclohex-1-en-1-yl)oxy)trimethylsilane 
• 930-68-7 cyclohexenone 
• 1197207-71-8 AZADO+Cl- 
• 1352617-47-0 C₉H₁₄NO⁽¹⁺⁾*ClO₄^(1-) 
• 1352617-22-1 1-(azaadamantane-N-oxyl)-1-trimethylsilyloxy-3-(3-butenyl)cyclohex-2-ene 
• 1197207-73-0 C₉H₁₄NO⁽¹⁺⁾*NO₃^(1-) 
• 57625-08-8 2-azatricyclo[3.3.1.1^3,7]dec-2-yloxidanyl 

Downstream Products

• 121363-31-3 3-(but-3-en-1-yl)-3-methylcyclohexan-1-one 
• 17605-08-2 2-allyl-3-methyl-2-cyclohexen-1-one 
• 84599-68-8 (1R,4R,6R)-Tricyclo[4.4.0.0^1,4]decan-7-one 
• 84599-65-5 (1S,3aR,7aR)-Hexahydro-1,3a-methano-inden-7-one 
• 84599-65-5 (1R,3aS,7aR)-Hexahydro-1,3a-methano-inden-7-one 
• 905832-81-7 (S)-3-(but-3-enyl)-3-methylcyclohexan-1-one 
• 2979-19-3 3,3-dimethylcyclohexanone 
• 1619908-82-5 C₁₇H₂₄O₅ 
• 1619908-74-5 1,1-dimethyl 2-[2-(3-oxocyclohex-1-enyl)ethyl]cyclopropane-1,1-dicarboxylate 
• 1352139-32-2 C₁₈H₂₁NO₃ 
• 1097631-09-8 (±)-3-(3-butenyl)-cyclohex-2-en-1-ol 
• 121363-32-4 2-((S)-3-But-3-enyl-3-methyl-cyclohexylidene)-[1,3]dithiane 
• 121363-37-9 (S)-3-But-3-enyl-3-methyl-cyclohexanecarboxylic acid methyl ester 
• 121363-33-5 (S)-3-But-3-enyl-3-methyl-cyclohexanecarboxylic acid 

Relevant articles and documents

Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO +BF4-) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

Stereoselective aziridination of cyclic allylic alcohols using chloramine-T

The stereoselective aziridination of a range of cyclic allylic alcohols using two different chloramine salts (4-MeC6H4SO 2NClNa, TsNClNa and t-BuSO2NClNa, BusNClNa) has been explored. The stereoselectivity of these reactions was highly dependent on the structure of the allylic alcohol and the chloramine salt. Generally, mixtures of cis- and trans-hydroxy aziridines were obtained, in which the major diastereomer was the cis-hydroxy aziridine, whilst complete cis- diastereoselectivity was observed in the aziridination of 1,3-disubstituted allylic alcohols. In each case studied, aziridination using BusNClNa gave higher cis-stereoselectivity than that observed for the same reaction using TsNClNa. Unexpectedly, application of the aziridination conditions to 1-substituted cyclopen-2-en-1-ols did not generate the aziridines. Instead, epoxy sulfonamides were obtained.

Enantioselective copper-catalyzed conjugate addition to trisubstituted cyclohexenones: Construction of stereogenic quaternary centers

Trimethyl- and triethylaluminum undergo enantioselective conjugate addition to 3-and 2-substituted cyclohexenones in the presence of catalytic amounts of a Cu salt and a phosphoramidite ligand L* (see scheme). Thus, chiral quaternary centers can be built with up to 96.6% ee. Functionalized enones lead to bicyclic structures by a subsequent aldol reaction.