226896-62-4

Basic information

• Product Name: 2-(4-biphenyl-4-yl-cuban-1-yl)-1,2-dihydro-naphthalen-1-ol
• Synonyms: 2-(4-biphenyl-4-yl-cuban-1-yl)-1,2-dihydro-naphthalen-1-ol
• CAS NO: 226896-62-4
• Molecular Weight: 400.52
• Mol File: 226896-62-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-biphenyl-4-yl-cuban-1-yl)-1,2-dihydro-naphthalen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-biphenyl-4-yl-cuban-1-yl)-1,2-dihydro-naphthalen-1-ol(226896-62-4)
• EPA Substance Registry System: 2-(4-biphenyl-4-yl-cuban-1-yl)-1,2-dihydro-naphthalen-1-ol(226896-62-4)

Safety Data

• Hazardous Substances Data: 226896-62-4(Hazardous Substances Data)

Upstream product

• 573-57-9 1,4-dihydronaphthalene-1,4-epoxide 
• 226896-61-3 1-biphenyl-4-yl-4-iodo-cubane 
• 32846-66-5 cubane-1,4-dicarboxylic acid 
• 97229-08-8 1,4-diiodocubane 

Relevant articles and documents

Building with cubane-1,4-diyl. Synthesis of aryl-substituted cubanes, p- [n]cubyls, and cubane-separated bis(arenes)

On treatment with an organolithium 1,4-diiodocubane generates cubane- 1,4-diyl, a highly reactive species, shown here to be a versatile precursor to numerous aryl substituted cubanes, available now for the first time in high yield. The diyl is demonstrated to provide a good route to bicubyl and its derivatives. A kind of 'living polymerization' of the diyl is developed to give the p-[n]cubyls. These oligomers are rigid rods made up to cubanes linked together at the 1 and 4 positions, each cubane adding ~4.15 ? to the length. The properties of these rods, some more than 15 ? long, are discussed; as are methods for modifying their solubility. X-ray crystallographic analyses of some of these compounds are presented, with emphasis on packing parameters.