226947-05-3

Basic information

• Product Name: Mo(S₂CN(CH₂CH₃)2)2Cl₂(NC₆H₄NH₂)
• CAS NO: 226947-05-3
• Molecular Weight: 569.519
• Mol File: 226947-05-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mo(S₂CN(CH₂CH₃)2)2Cl₂(NC₆H₄NH₂)(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(S₂CN(CH₂CH₃)2)2Cl₂(NC₆H₄NH₂)(226947-05-3)
• EPA Substance Registry System: Mo(S₂CN(CH₂CH₃)2)2Cl₂(NC₆H₄NH₂)(226947-05-3)

Safety Data

• Hazardous Substances Data: 226947-05-3(Hazardous Substances Data)

Upstream product

• 57146-54-0 oxodichloro-bis-diethyldithiocarbamato molybdenum(VI) 
• 106-50-3 1,4-phenylenediamine 

Relevant articles and documents

Para-Functionalised Molybdenum Aryl-Imido Complexes [Mo(NAr)(S2CNEt2)2Cl2] and Diimido Complexes [{Mo(S2CNEt2)2Cl2} 2(μ-1,5-NC10H6N)] and [{Mo(S2)(S2CNEt2)2}2 (μ-p-NC6H4N)]

A range of para-substituted aryl-imido complexes [Mo(NAr)(S2CNEt2)2Cl2] has been prepared upon reaction of [MoO(S2CNEt2)2Cl2] with substituted anilines. With diamines similar mononuclear complexes result containing a pendant amino group which is deactivated towards further addition of molybdenum. This is attributed to the significant reduction in basicity of the remaining amine functionality upon coordination of the first to the electron-deficient molybdenum(VI) centre, and suggests that the two centres communicate strongly via the π-conjugated organic linking group. Diimido-bridged [{Mo(S2CNEt2)Cl2}2(μ-1,5-NC 10H6N)] was isolated from the reaction with naphthalene-1,5-diamine, while reaction of [MoO2(S2CNEt2)2] with para-phenylene diisocyanate afforded [{Mo(S2)(S2CNEt2)2} 2(μ-p-NC6H4N)].