226985-09-7

Basic information

• Product Name: [((S)-2-Acetylamino-4-oxo-4-phenyl-butyryl)-methoxycarbonylmethyl-amino]-acetic acid methyl ester
• Synonyms: [((S)-2-Acetylamino-4-oxo-4-phenyl-butyryl)-methoxycarbonylmethyl-amino]-acetic acid methyl ester
• CAS NO: 226985-09-7
• Molecular Weight: 378.382
• Mol File: 226985-09-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((S)-2-Acetylamino-4-oxo-4-phenyl-butyryl)-methoxycarbonylmethyl-amino]-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [((S)-2-Acetylamino-4-oxo-4-phenyl-butyryl)-methoxycarbonylmethyl-amino]-acetic acid methyl ester(226985-09-7)
• EPA Substance Registry System: [((S)-2-Acetylamino-4-oxo-4-phenyl-butyryl)-methoxycarbonylmethyl-amino]-acetic acid methyl ester(226985-09-7)

Safety Data

• Hazardous Substances Data: 226985-09-7(Hazardous Substances Data)

Upstream product

• 39987-25-2 dimethyl iminodiacetate hydrochloride 
• 200730-91-2 (S)-2-Acetylamino-4-oxo-4-phenyl-butyric acid 
• 41148-79-2 (S)-N-acetyl-L-aspartic anhydride 
• 71-43-2 benzene 

Relevant articles and documents

Regio- and stereoselective 1,6-photocyclization of aspartic acid- derived chiral γ-ketoamides[1]

Chiral α-acylamino γ-ketoamides 2 were irradiated and regioisomeric 1,6-cyclization products 3 and 4 obtained in high yields. Symmetrically N,N- disubstituted substrates 2a,b reacted diastereoselectively to give the all- cis products 3a,b in high yields. High 1,3-asymmetric induction was also observed for the unsymmetrically N,N-disubstituted 2d and 2e. The stereoselectivity of these reactions is discussed in terms of SOC-controlled spin inversion geometries.