22757-62-6

Basic information

• Product Name: 2-(2-nitrobenzyl)-1H-indene-1,3(2H)-dione
• Synonyms: 2-(2-nitrobenzyl)-1H-indene-1,3(2H)-dione
• CAS NO: 22757-62-6
• Molecular Weight: 281.268
• Mol File: 22757-62-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-nitrobenzyl)-1H-indene-1,3(2H)-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-nitrobenzyl)-1H-indene-1,3(2H)-dione(22757-62-6)
• EPA Substance Registry System: 2-(2-nitrobenzyl)-1H-indene-1,3(2H)-dione(22757-62-6)

Safety Data

• Hazardous Substances Data: 22757-62-6(Hazardous Substances Data)

Upstream product

• 606-23-5 1H-indene-1,3(2H)-dione 
• 552-89-6 2-nitro-benzaldehyde 

Relevant articles and documents

Intramolecular Pd-catalyzed reductive amination of enolizable sp3-C-H bonds

A palladium-catalyzed reductive cyclization of nitroarenes has been designed to construct sp3-C-NHAr bonds from sp3-C-H bonds by using an enolizable nucleophile to intercept a nitrosoarene intermediate. Exposure of ortho-substituted nitroarenes to 5 mol ?% of Pd(OAc)2 and 10 mol ?% of phenanthroline under 2 atm of CO constructs partially saturated 5-, 6-, or 7-membered N-heterocycles using α-pyridyl carboxylates, malonates, 1,3-dimethylbarbituric acid, 1,3-diones, or difurans as the nucleophile.