228251-88-5

Basic information

• Product Name: methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienoate
• Synonyms: methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienoate
• CAS NO: 228251-88-5
• Molecular Weight: 707.154
• Mol File: 228251-88-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienoate(228251-88-5)
• EPA Substance Registry System: methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienoate(228251-88-5)

Safety Data

• Hazardous Substances Data: 228251-88-5(Hazardous Substances Data)

Upstream product

• 62992-46-5 1-(tetrahydropyranyloxy)-4-pentyn 
• 228251-86-3 2(E),8(Z)-(4R,5S)-10-(tert-butyldiphenylsilyl)oxy-N-methoxy-9-methoxymethyl-N,4,8-trimethyl-5-(triisopropylsilyl)oxy-2,8-decadienamide 
• 228251-82-9 (Z)-<3(2R,3S),4R>-3-<8-(tert-butyldiphenylsilyl)oxy-3-hydroxy-7-methoxymethyl-2,6-dimethyl-6-octenoyl>-4-benzyl-2-oxazolidinone 
• 228251-84-1 (Z)-(2R,3S)-8-(tert-butyldiphenylsilyl)oxy-N-methoxy-7-methoxymethyl-N,2,6-trimethyl-3-(triisopropylsilyl)oxy-6-octenamide 
• 228251-85-2 (Z)-(2R,3S)-8-(tert-butyldiphenylsilyl)oxy-7-methoxymethyl-2,6-dimethyl-3-(triisopropylsilyl)oxy-6-octenal 
• 228251-83-0 (Z)-(2R,3S)-8-(tert-butyldiphenylsilyl)oxy-3-hydroxy-N-methoxy-7-methoxymethyl-N,2,6-trimethyl-6-octenamide 
• 228251-78-3 (E)-1-(tert-butyldiphenylsilyl)oxy-2-methoxymethyl-3-methyl-6-(tetrahydropyranyl)oxy-2-hexene 
• 228251-79-4 (Z)-6-(tert-butyldiphenylsilyl)oxy-5-methoxymethyl-4-methyl-4-hexenol 
• 228251-80-7 (Z)-6-(tert-butyldiphenylsilyl)oxy-5-methoxymethyl-4-methyl-4-hexenal 
• 228251-76-1 methyl 2-methoxymethyl-3-methyl-6-(tetrahydropyranyl)oxy-2-hexenoate 
• 228251-77-2 (E)-2-methoxymethyl-3-methyl-6-(tetrahydropyranyl)oxy-2-hexenol 
• 104803-57-8 6-(tetrahydro-pyran-2-yloxy)-hex-2-ynoic acid methyl ester 
• 5390-04-5 pent-1-yn-5-ol 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 

Downstream Products

• 228251-90-9 methyl 4(Z),6(E),12(Z)-(8R,9S)-14-(tert-butyldiphenylsilyl)oxy-2-cyano-13-methoxymethyl-8,12-dimethyl-9-(triisopropylsilyl)oxy-4,6,12-tetradecatrienoate 
• 228251-89-6 methyl 2(Z),4(E),10(Z)-(6R,7S)-12-(tert-butyldiphenylsilyl)oxy-11-methoxymethyl-6,10-dimethyl-7-(triisopropylsilyl)oxy-2,4,10-dodecatrienol 

Relevant articles and documents

Transannular Diels-Alder studies on the asymmetric synthesis of (+)- maritimol

Assembly of 13-membered TCC macrocyclic trienes are described and their transannular Diels-Alder reaction are investigated as a model study for the asymmetric synthesis of the ABC-ring system of (+)-maritimol. Albeit the original expectations that the pro-3(S)- and 4(R)-functionalities induce perfect absolute and relative control in the strategic step has not been fully met, a position at pro-12(R) complying with these requirements is recognized.