22829-72-7

Basic information

• Product Name: HRh(CO)(P(OCH₃C₆H₄)3)3
• CAS NO: 22829-72-7
• Molecular Weight: 1189.03
• Mol File: 22829-72-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: HRh(CO)(P(OCH₃C₆H₄)3)3(CAS DataBase Reference)
• NIST Chemistry Reference: HRh(CO)(P(OCH₃C₆H₄)3)3(22829-72-7)
• EPA Substance Registry System: HRh(CO)(P(OCH₃C₆H₄)3)3(22829-72-7)

Safety Data

• Hazardous Substances Data: 22829-72-7(Hazardous Substances Data)

Upstream product

• 2622-08-4 tri(O-methylphenyl)phosphite 

Relevant articles and documents

Hex-1-ene hydroformylation catalyzed by Rh(acac)2 modified with amines, formation of reactive HRh(CO)3 und unreactive Rh4(CO)84 species

Pyridines and amines have been used as modifying ligands in the hex-1-ene hydroformylation reaction catalyzed by Rh(acac)2.Aldehydes (n + iso) were obtained in 80-85 percent yield.The active form of the catalyst has been isolated as the solid HRh(CO)3.Another complex formed in the reaction of Rh(acac)2 with H2 and CO in the presence of pyridine, Rh4(CO)84, is catalytically inactive.