229323-96-0

Basic information

• Product Name: Hydroperoxide, [4-(1,1-dimethylethyl)cyclohexylidene]bis-
• CAS NO: 229323-96-0
• Molecular Formula: C10H20O4
• Molecular Weight: 204.266
• Mol File: 229323-96-0.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Hydroperoxide, [4-(1,1-dimethylethyl)cyclohexylidene]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroperoxide, [4-(1,1-dimethylethyl)cyclohexylidene]bis-(229323-96-0)
• EPA Substance Registry System: Hydroperoxide, [4-(1,1-dimethylethyl)cyclohexylidene]bis-(229323-96-0)

Safety Data

• Hazardous Substances Data: 229323-96-0(Hazardous Substances Data)

Upstream product

• 169294-55-7 4-tert-butyl-1-methoxy-cyclohexyl hydroperoxide 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 126781-85-9 1-(tert-butyl)-4-(methoxymethylene)cyclohexane 

Downstream Products

• 960121-25-9 1,1-di(triethylsilyldioxy)-4-tert-butylcyclohexane 
• 1427511-80-5 4-tert-butyl-1,1-bis(decylperoxy)cyclohexane 
• 1354978-61-2 1-acetyldioxy-1-tert-butyldimethylsilyldioxy-4-tert-butylcyclohexane 
• 1354978-50-9 1-acetyldioxy-1-triethylsilyldioxy-4-tert-butylcyclohexane 
• 1354978-56-5 1,1-diacetyldioxy-4-tert-butylcyclohexane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 1186514-15-7 1-benzoyldioxy-1-hydroperoxy-4-tert-butylcyclohexane 
• 1186514-13-5 1-acetyldioxy-1-hydroperoxy-4-tert-butylcyclohexane 
• 1186514-14-6 4-tert-butyl-1-hydroperoxycyclohexyl ethyl carbonoperoxoate 
• 869298-35-1 benzhydryl-[3-(8-tert-butyl-1,2-dioxaspiro[4.5]dec-3-yl)-2,2-dimethylpropyl]dimethylsilane 
• 869298-33-9 benzhydryl-(8-tert-butyl-1,2-dioxaspiro[4.5]dec-3-ylmethyl)-dimethylsilane 

Relevant articles and documents

Efficient synthesis of gem-dihydroperoxides with molecular oxygen and anthraquinone under visible light irradiation with fluorescent lamp

We developed an efficient dihydroperoxidation protocol of various carbonyl compounds with molecular oxygen and anthraquinone in 2-propanol under visible light irradiation with a fluorescent lamp, which produced corresponding gem-dihydroperoxides in high yields.

Synthesis, crystal structure and anti-malarial activity of novel spiro- 1,2,4,5-tetraoxacycloalkanes

(Cycloalkylidene)bishydroperoxides 3 react with 1,n-dihaloalkanes (n = 3-6) in the presence of CsOH-H2O in DMF affording the corresponding spiro- 1,2,4,5-tetraoxacycloalkanes 4 in moderate yields. Compound 4ba exhibits significant antimalarial activity in vitro against P. falciparum.

Activation of aqueous hydrogen peroxide for non-catalyzed dihydroperoxidation of ketones by azeotropic removal of water

Cyclic and acyclic ketones were selectively converted to gem-dihydroperoxides in 72-99% yield with 30% aq. hydrogen peroxide by azeotropic distillation of water from the reaction mixture without any catalyst. The reactions were more selective than with 100% H2O2 and due to neutral conditions also less stable products could be obtained.

Oxidative cleavage of C=C bonds with singlet molecular oxygen generated from monoacetylated bishydroperoxides

The oxidative cleavage of C=C bonds adjacent to aryl and alkyl moieties was efficiently achieved with monoacetylated bishydroperoxides. The main active oxidant used in this reaction was singlet molecular oxygen, which was generated in situ from the base-mediated fragmentation of monoacetylated bishydroper oxides. All the reactions proceeded smoothly at room temperature to furnish the respective carbonyl compounds in good yields within short reaction times. Georg Thieme Verlag Stuttgart · New York.