22950-23-8Relevant articles and documents
Direct palladium(0)-catalyzed amination of allylic alcohols with aminonaphthalenes
Shue, Yi-Jen,Yang, Shyh-Chyun,Lai, Hwe-Chen
, p. 1481 - 1485 (2003)
The direct activation of C-O bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium reagents. The palladium-catalyzed amination of allylic alcohols using aminonaphthalenes gave N-all
PEG-4000-promoted palladium-catalyzed N-allylation in water: Aminonaphthalene as an example
Shih, Chun-Jen,Shue, Yi-Jen,Yang, Shiang-Yu,Yang, Shyh-Chyun
, p. 550 - 555 (2012/11/07)
An environmentally friendly, efficient catalytic process using palladium associated with ligands in a PEG4000-water system leading to N-allylation was described in this study. PEG-4000 was found to improve the palladium-catalyzed allylic amination of allylic acetates with aminonaphthalenes and gave overall good to high yields of the corresponding N-allylic aminonaphthalenes. Copyright
Synthesis of azepine- and azocine-annulated heterocycles by aromatic aza-Claisen rearrangement and ring-closing metathesis
Majumdar,Samanta, Srikanta,Chattopadhyay, Buddhadeb,Nandi, Raj Kumar
experimental part, p. 863 - 869 (2010/09/18)
Syntheses of hitherto unreported azepine- and azocine-annulated heterocycles have been developed in excellent yields via a catalyzed aromatic aza-Claisen rearrangement followed by ring-closing metathesis using Grubbs first-generation catalyst. Georg Thiem