22981-96-0Relevant articles and documents
REACTION OF cis-BICYCLONONA-3,7-DIENE WITH IODINE. SYNTHESIS OF TRICYCLO3,7>NONA-4,8-DIENE (BREXA-4,8-DIENE)
Lukovskaya, E. V.,Bobyleva, A. A.,Pekhk, T. I.,Dubitskaya, N. F.,Petrushenkova, I. A.,Belikova, N. A.
, p. 1311 - 1317 (2007/10/02)
The reaction of iodine with cis-bicyclonona-3,7-diene is accompanied by regioselective and stereoselective transannular cyclization with the formation of endo-4,exo-8-diiodobrexane.Methods were developed for the production of endo-9-iodobrex-4-ene and brexa-4,8-diene with yields of 26 and 20percent respectively.The mechanism of transannular cyclization is discussed.