230-07-9

Basic information

• Product Name: 4,7-PHENANTHROLINE
• Synonyms: OTAVA-BB BB7110952551;P-PHENANTHROLINE;P-PHENANTHROLINE (4,7);AKOS BBS-00001338;AKOS 92616;4,7-PHENANTHROLINE;1,8-Diazaphenanthrene;Pseudophenanthroline
• CAS NO: 230-07-9
• Molecular Formula: C₁₂H₈N₂
• Molecular Weight: 180.21
• Product Categories: Heterocyclic Compounds;Heterocyclic Building Blocks;N-Containing;Others
• Mol File: 230-07-9.mol
• Article Data: 0

Chemical Properties

• Melting Point: 172-174 °C(lit.)
• Boiling Point: 303.03°C (rough estimate)
• Flash Point: 164.8 °C
• Appearance: White to beige/Crystalline Powder
• Density: 1.1836 (rough estimate)
• Vapor Pressure: 3.38E-05mmHg at 25°C
• Refractive Index: 1.5200 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 4.30±0.10(Predicted)
• Water Solubility: 1.442g/L(temperature not stated)
• CAS DataBase Reference: 4,7-PHENANTHROLINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4,7-PHENANTHROLINE(230-07-9)
• EPA Substance Registry System: 4,7-PHENANTHROLINE(230-07-9)

Safety Data

• Hazard Codes: Xn
• Statements: 22-41-36/37/38
• Safety Statements: 26-39-36
• WGK Germany: 3
• Hazardous Substances Data: 230-07-9(Hazardous Substances Data)

Usage

Description

4,7-Phenanthroline is an organic compound that is known for its ability to form complexes with various metal ions, particularly transition metals. It is characterized by its nitrogen-containing heterocyclic structure, which allows it to act as a bidentate ligand in coordination chemistry. This property makes it a versatile compound for use in a wide range of applications.

Uses

Used in Coordination Chemistry:
4,7-Phenanthroline is used as a ligand in coordination chemistry for the formation of metal complexes. Its ability to chelate with metal ions, such as ruthenium, results in the creation of stable and well-defined structures with potential applications in various fields.
Used in the Preparation of Cyclic Tetranuclear Half-Sandwich Ruthenium(II) Complexes:
4,7-Phenanthroline is employed as a chelating agent for the synthesis of cyclic tetranuclear half-sandwich ruthenium(II) complexes. These complexes exhibit unique properties and potential applications in areas such as catalysis, sensing, and materials science.
Used in the Preparation of Positively Charged Homochiral Cyclic Trinuclear Metallacalix[3]arene Species:
4,7-Phenanthroline is utilized as a building block in the construction of positively charged homochiral cyclic trinuclear metallacalix[3]arene species. These complex structures have potential applications in supramolecular chemistry, molecular recognition, and chiral separation processes.

InChI:InChI=1/C12H8N2/c1-3-9-10-4-2-8-14-12(10)6-5-11(9)13-7-1/h1-8H

Upstream product

• 60-09-3 aniline yellow 
• 56-81-5 glycerol 
• 100-01-6 4-nitro-aniline 

Downstream Products

• 36861-70-8 3,8-diphenyl-[4,7]phenanthroline 
• 101936-20-3 3-p-tolyl-4,7-phenanthroline 
• 102079-39-0 N,N-dimethyl-4-[4,7]phenanthrolin-3-yl-aniline 
• 93656-09-8 3-phenyl-[4,7]phenanthroline 
• 3723-32-8 3,3'-bipyridine-2,2'-dicarboxylic acid 
• 134978-42-0 dimethyl N-p-chlorobenzoyl-3,4-dihydro-4,7-phenathroline-3-phosphonate 
• 134978-34-0 cis-dimethyl N,N'-di-p-chlorobenzoyl-3,4,7,8-tetrahydro-4,7-phenathroline-3,8-diphosphonate 

Related news

Cyclic tetranuclear half-sandwich ruthenium(II) complexes with 4,7-PHENANTHROLINE (cas 230-07-9) and hydroxo bridges: Crystal structure, solution behaviour and binding to nucleosides09/30/2019

The reaction between [(η 6 -p-cymene)Ru(H 2 O) 3 ]X 2 and 4,7-phenanthroline (phen) leads to the formation of the rectangular tetranuclear complexes [(η 6 -p-cymene) 4 Ru 4 (μ-4,7-phen-N 4 ,N 7 ) 2 (μ-OH) 4 ...detailed

Vanillin Esters of Aliphatic Acids in the Synthesis of 4,7-PHENANTHROLINE (cas 230-07-9) Derivatives09/29/2019

Condensation of vanillin esters of aliphatic acids with 6-aminoquinoline and cyclic c-diketones (1,3-cyclohexanedione and dimedone) afforded new 2-methoxy-4-(11-oxo-7,8,9,10,11,12-hexahydrobenzo[b][4,7]phenanthrolin-12-yl)phenyl esters of carboxylic acids.detailed