23114-01-4

Basic information

• Product Name: Benzenesulfonamide, N,4-dimethyl-N-nitro-
• CAS NO: 23114-01-4
• Molecular Formula: C8H10N2O4S
• Molecular Weight: 230.244
• Mol File: 23114-01-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N,4-dimethyl-N-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N,4-dimethyl-N-nitro-(23114-01-4)
• EPA Substance Registry System: Benzenesulfonamide, N,4-dimethyl-N-nitro-(23114-01-4)

Safety Data

• Hazardous Substances Data: 23114-01-4(Hazardous Substances Data)

Upstream product

• 640-61-9 N-methyl-p-toluenesulfonylamide 
• 20607-12-9 sodium salt of N-methyl toluenesulfonamide 
• 16697-83-9 N-methyl-N-tosylacetamide 
• 1099-76-9 N,N'-dimethyl-N,N'-methanediyl-bis-toluene-4-sulfonamide 
• 63316-79-0 N-methyl-N-morpholin-4-ylmethyl-toluene-4-sulfonamide 

Downstream Products

• 649-15-0 N,N-diethyl-4-methylbenzenesulfonamide 
• 66074-95-1 4',5,7-trimethoxyflavanone 
• 1428243-26-8 (3R,4S)-benzyl 3-(2-bromoacetyl)-4-ethylpyrrolidine-1-carboxylate 
• 67-56-1 methanol 
• 104-15-4 toluene-4-sulfonic acid 
• 640-61-9 N-methyl-p-toluenesulfonylamide 
• 70-55-3 toluene-4-sulfonamide 

Relevant articles and documents

Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing compounds in acetonitrile: Chemical origin of NO2 release and capture

(Chemical Equation Presented) The first heterolytic and homolytic N(O)-NO2 bond dissociation energy scales of three types Y-nitro (Y = N, O) compounds and corresponding radical anions in acetonitrile were established by using titration calorimetry combined with relevant electrochemical data through proper thermodynamic cycles.

Reaction of N-Nitroso- and N-Nitro-N-alkylamides with Amines

Several N-nitroso- and N-nitrocarboxamides have been characterized by 1H and 13C NMR spectroscopy.These compounds react with ammonia and aliphatic amines to afford mainly carboxamides of general formula RCONH2, RCONHR', or RCONR'R''.N-Nitrosocarboxamides and aromatic amines give poor yields of RCONHAr; by contrast, N-nitrocarboxamides and aromatic amines lead to RCONHAr in good yields.The higher thermal stability of the N-nitroamides as compared to N-nitrosoamides is advantageous in this connection; nevertheless, the principal advantage of the NNO2 group appears to be that it activates the nucleophilic attack to the carbonyl of the amide function more than the NNO group, as has been demonstrated by competitive experiments.The reaction of N-nitroso- and N-nitro-N-methylsulfonamides with ammonia and diethylamine has been studied as well; whereas N-methyl-N-nitro-p-toluenesulfonamide reacts as N-nitrocarboxamides, transnitration is predominant with N-methyl-N-nitroso-p-toluenesulfonamide.

NITRATION OF N-ALKYLAMIDES

-