233272-56-5Relevant articles and documents
Regiospecific acylation of acetals. A convenient method to obtain β- methoxyvinyl trichloromethyl ketones
Martins, Marcos A.P.,Bastos, Giovani P.,Bonacorso, Helio G.,Zanatta, Nilo,Flores, Alex F.C.,Siqueira, Geonir M.
, p. 4309 - 4312 (1999)
The regiochemistry of the acylation of enol ethers, generated in situ, from acetals of unsymmetrical ketones is reported. These results demonstrate a convenient one-pot method to obtain a series of β-methoxyvinyl trichloromethyl ketones [CCl3COCH=C(OMe)R, where R=Et, n-Bu, i-Pt, (CH2)2C(OMe)=CHC(O)CCl3 and (CH2)5CO2CH3)] in high yields.