23377-53-9Relevant articles and documents
Ultraviolet-Visible Spectroscopic Studies on Manganese and Rhenium Oxide Fluorides in Low-temperature Matrices
Brisdon, Alan K.,Holloway, John H.,Hope, Eric G.,Townson, Paul J.,Levason, William,Ogden, J. Steven
, p. 3127 - 3132 (1991)
Five high-oxidation-state metal oxide fluorides, MnO3F, ReO3F, ReO2F3, ReOF5 and ReOF4 have been isolated as molecular species in inert-gas matrices at low temperatures, and studied by IR and UV/VIS spectroscopy.In particular, the electronic spectra are described and the principal charge-transfer bands assigned using the optical electronegativity model.This suggested that a new value for χopt(F-) of 3.6 is appropriate for transition-metal oxide fluorides.