23415-66-9

Basic information

• Product Name: (3-chlorophenyl)diphenylphosphine
• Synonyms: (3-chlorophenyl)diphenylphosphine
• CAS NO: 23415-66-9
• Molecular Weight: 296.736
• Mol File: 23415-66-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (3-chlorophenyl)diphenylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: (3-chlorophenyl)diphenylphosphine(23415-66-9)
• EPA Substance Registry System: (3-chlorophenyl)diphenylphosphine(23415-66-9)

Safety Data

• Hazardous Substances Data: 23415-66-9(Hazardous Substances Data)

Upstream product

• 40841-62-1 (diphenylphosphino)(p-tolyl)methanone 
• 86364-03-6 3-chloro-1-trifluoromethanesulfonyloxybenzene 
• 1079-66-9 chloro-diphenylphosphine 
• 4376-01-6 sodium diphenylphosphide 
• 541-73-1 1,3-Dichlorobenzene 
• 1031-93-2 diphenyl(p-tolyl)phosphine 
• 603-35-0 triphenylphosphine 
• 7650-91-1 benzyldiphenylphosphane 
• 6002-34-2 tert-butyldiphenylphosphine 
• 1257322-33-0 H₃B(PPh₂(C₆H₄Cl)) 
• 6372-40-3 isopropyldiphenylphosphine 
• 15475-27-1 potassium diphenylphosphine 
• 829-85-6 diphenylphosphane 
• 625-99-0 3-iodochlorobenzene 

Relevant articles and documents

Palladium-Catalyzed C-P(III) Bond Formation by Coupling ArBr/ArOTf with Acylphosphines

Palladium-catalyzed C-P bond formation reaction of ArBr/ArOTf using acylphosphines as differential phosphination reagents is reported. The acylphosphines show practicable reactivity with ArBr and ArOTf as the phosphination reagents, though they are inert to the air and moisture. The reaction affords trivalent phosphines directly in good yields with a broad substrate scope and functional group tolerance. This reaction discloses the acylphosphines' capability as new phosphorus sources for the direct synthesis of trivalent phosphines.

Palladium-catalyzed C–P(III) bond formation reaction with acylphosphines as phosphorus source

Palladium-catalyzed C–P(III) bond formation reaction employing acylphosphines as the phosphorus source was developed. Under the optimized conditions, acylphosphines could react with aryl halides directly affording trivalent phosphines in up to 94% yield.

Synthesis of alkyl- and aryldiphenylphosphines via electrogenerated magnesium chloride diphenylphosphanide

A two-steps procedure allowing the formation of alkyldiphenylphosphines and aryldiphenylphosphines in good yield is described. It relies on the electrochemical preparation of magnesium chloride diphenylphosphanide and its subsequent coupling with either alkyl halides or aryl fluorides.