23556-91-4Relevant articles and documents
Highly selective isomerization of allyloxyalcohols to cyclic acetals or 1-propenyloxyalcohols
Urbala, Magdalena,Ku?nik, Nikodem,Krompiec, Stanis?aw,Rzepa, Józef
, p. 1203 - 1206 (2004)
Highly selective isomerization of allyloxyalcohols either to 1-propenyl derivatives or to cyclic acetals of propanal depending on the transition metal (Ru, Rh) complex used is described together with a proposed explanation of an alternative reaction, which permits broad application of the described method.
A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters
Krompiec, Stanis?aw,Penczek, Robert,Ku?nik, Nikodem,Ma?ecki, Jan Grzegorz,Matlengiewicz, Marek
, p. 137 - 140 (2007/10/03)
Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by [RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and o