2359-69-5

Basic information

• Product Name: Cyclohexanepropanoic acid, 2-methylene-, methyl ester
• CAS NO: 2359-69-5
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 2359-69-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanepropanoic acid, 2-methylene-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanepropanoic acid, 2-methylene-, methyl ester(2359-69-5)
• EPA Substance Registry System: Cyclohexanepropanoic acid, 2-methylene-, methyl ester(2359-69-5)

Safety Data

• Hazardous Substances Data: 2359-69-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 73926-47-3 1-(1-cyclohexenyl)-3-buten-2-one 
• 75-09-2 dichloromethane 
• 10407-33-7 methyl 3-(2-oxocyclohexyl)propionate 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Relevant articles and documents

Cyclization of Substituted 5-Hexenyl Radicals as a Model for Photocyclization of 1,5-Hexadien-3-ones

An examination of substituent effects upon the photochemistry of a number of 1,5-hexadien-3-ones reveals a close parallel with those observed in the cyclization of 5-hexenyl radicals and permits for the first time a rationalization for variations in the regiospecificity of the intramolecular cycloaddition reactions of these dienones.

Regiochemical Control in Intramolecular Photochemical Reactions of 1,5-Hexadien-3-ones and 1-Acyl-1,5-hexadienes

Both 1,5-hexadien-3-ones (7) and 1-acyl-1,5-hexadienes (8) generally undergo intramolecular photochemical cyclization by way of 1,5 (crossed) closure (see 2), as do other derivatives of 1,5-hexadienes (1).Through study of the photochemistry of 14 members