24041-60-9

Basic information

• Product Name: (+)-ISOPINOCAMPHEOL
• Synonyms: (+)-ISOPINOCAMPHEOL;ISOPINOCAMPHEOL, (+)-;(1S,2S,3S,5R)-(+)-ISOPINOCAMPHEOL;3-PINANOL;[1S-(1alpha,2beta,3alpha,5alpha)]-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol;(1S,2S,3S,5R)-Pina-3β-ol;(1S,2S,5R)-(+)-Isopinocampheol;(1α,5α)-2α,7,7-Trimethylbicyclo[3.1.1]heptan-3β-ol
• CAS NO: 24041-60-9
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• EINECS: 248-657-4
• Mol File: 24041-60-9.mol
• Article Data: 22

Chemical Properties

• Melting Point: 52-55 °C
• Boiling Point: 219℃
• Flash Point: 93.4℃
• Appearance: /
• Density: 0.96g/cm³
• PKA: 15.35±0.60(Predicted)
• CAS DataBase Reference: (+)-ISOPINOCAMPHEOL(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-ISOPINOCAMPHEOL(24041-60-9)
• EPA Substance Registry System: (+)-ISOPINOCAMPHEOL(24041-60-9)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 24041-60-9(Hazardous Substances Data)

Usage

General Description

(+)-ISOPINOCAMPHEOL, also known as 1,1,6-Trimethyl-2-exo-isobornyl cyclohexanol, is a naturally occurring compound found in the essential oil of rosemary. It is a bicyclic monoterpene alcohol with a characteristic fresh and herbal aroma. This chemical has been studied for its various biological activities, including antioxidant, anti-inflammatory, and antimicrobial properties. It has also been investigated for its potential application in fragrance and flavor industries. The compound has shown promising potential as an ingredient in cosmetic and pharmaceutical products due to its beneficial properties. Research on (+)-ISOPINOCAMPHEOL continues to explore its potential applications in various fields.

InChI:InChI=1S/C12H22O/c1-8-9(13)6-11(4)7-12(8,5)10(11,2)3/h8-9,13H,6-7H2,1-5H3/t8-,9+,11+,12+/m0/s1

Upstream product

• 1686-14-2 (1R,2R,4S,6R)-2,7,7-trimethyl-3-oxatricyclo[4.1.1.0.^2,4]octane 
• 4165-78-0 (Z)-(1-ethylpropenyl)benzene 
• 4165-86-0 (E)-(1-ethylpropenyl)benzene 
• 7785-26-4 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene 
• 7785-26-4 (-)-α-pinene 
• 80-56-8 Pinene 
• 14575-92-9 2,3-epoxy-cis-pinane 
• 401788-78-1 (R)-7-Benzyloxy-2-methyl-heptanal 
• 590-18-1 (Z)-2-Butene 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 768-00-3 (E)-2-phenyl-2-butene 
• 767-99-7 (Z)-2-phenylbut-2-ene 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 766-90-5 cis-1-phenyl-1-propylene 

Downstream Products

• 14575-93-0 isopinocamphone 
• 14575-99-6 phthalic acid mono-((1S:2S:3S)-pinanyl-⁽³⁾-ester) 
• 14575-88-3 (1R,2S,3R)-3-(toluene-sulfonyl-⁽⁴⁾-oxy)-pinane 
• 114653-01-9 [4-(Tetrahydro-pyran-2-yloxy)-phenyl]-acetic acid (1R,2S,3R,5S)-2,6,6-trimethyl-bicyclo[3.1.1]hept-3-yl ester 
• 18358-53-7 pinocamphone 
• 497-36-9 Norborneol 
• 29342-53-8 norbornyl chloride 
• 117227-80-2 isopinocampheyl chloride 
• 19889-94-2 (1R)-(2endoH)-pinan-3endo-ol 
• 473-62-1 trans-pinocamphone 
• 36237-64-6 dihydrocarveol 
• 5362-50-5 4-methyl-3-penten-1-al 
• 102992-45-0 (1RS:2SR:3SR)-3-phenylcarbamoyloxy-pinane 
• 39166-57-9 (1R:2S:3R)-3-Acetoxy-pinan 

Relevant articles and documents

Preparation of crystalline (diisopinocampheyl)borane

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Synthesis and ultraviolet absorption characteristics of 4-arylidene isopinocamphones from α-pinene

A new series of 4-arylidene isopinocamphones were synthesized from α-pinene which is a natural chemical from pine tree and their ultraviolet absorption characteristics were investigated. (+)Isopinocamphone was obtained from α-pinene by hydroboration-oxidation and then it was reacted with benzaldehyde, p-methylbenzaldehyde, p -methoxybenzaldehyde, p-chlorobenzaldehyde, furfural and p -nitrobenzaldehyde in the presence of alkali catalysts to get 4-arylidene isopinocamphones including 2-benzylidene-4,6,6-trimethylbicyclo[3.1.1]heptan-3-one (1), 2,6,6-trimethyl-4-(4-methyl benzyl)bicyclo[3.1.1]heptane-3-one (2), 2-(4-methoxybenzylidene)-4,6,6-trimethylbicyclo[3.1.1] heptan-3-one ( 3 ), 2-(4-chlorobenzylidene)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-one (4 ), 2-(furan-2-methylene)-4,6,6-trimethylbicyclic [3.1.1] heptane-3-one (5) and 2,6,6-trimethyl-4-(4-nitrobenzylidene)bicyclo[3.1.1]heptan-3-one (6). he structures of 4-arylidene isopinocamphones were determined by FT-IR, 1H NMR, 13/C NMR and GC-MS technique. Their ultraviolet absorption characteristics and light stability was further examined. The results showed that compounds 1 , 2, 3 and 5 could be used as Btype UV absorbents, compounds 4 and 6 could be used as A-type UV absorbents and compounds 6 had both functions as UV-A and UVB types absorbents. The light stability sequence of these compounds was (2 ) > (1) ≈ (3) ≈ (4) ≈(6) > (5).

Minimal fluorous tagging strategy that enables the synthesis of the complete stereoisomer library of SCH725674 macrolactones

Four mixtures of four fluorous-tagged quasiisomers have been synthesized, demixed, and detagged to make all 16 stereoisomers of the macrocyclic lactone natural product Sch725674. A new bare-minimum tagging pattern needs only two tags-one fluorous and one nonfluorous-to encode four isomers. The structure of Sch725674 is assigned as (5R,6S,8R,14R,E)-5,6,8-trihydroxy-14- pentyloxacyclotetradec-3-en-2-one. Various comparisons of spectra of 32 lactones (16 with tags, 16 without) and 16 ester precursors (8 with tags, 8 without) provide insights into when and why related compounds have the same or different spectra.