24048-14-4

Basic information

• Product Name: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL
• Synonyms: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL;2,6,10-trimethyl-5,9-undecadien-1-ol,mixtureofisomers;2,6,10-trimethyl-9-undecadien-1-ol;5,9-Undecadien-1-ol,2,6,10-trimethyl-,(8CI,9CI);2,6,10-trimethylundeca-5,9-dienol;2,6,10-Trimethyl-5,9-undecadienol;2,6,10-TRIMETHYL-5 9-UNDECADIEN-1-OL 98% MIXTURE OF ISOMERS;Dihydroapofarnesol
• CAS NO: 24048-14-4
• Molecular Formula: C14H26O
• Molecular Weight: 210.36
• EINECS: 246-000-6
• Mol File: 24048-14-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 289.9°C (rough estimate)
• Flash Point: 134 °C
• Appearance: /
• Density: 0.87
• Vapor Pressure: 7.81E-05mmHg at 25°C
• Refractive Index: 1.474-1.479
• PKA: 15.01±0.10(Predicted)
• CAS DataBase Reference: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL(24048-14-4)
• EPA Substance Registry System: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL(24048-14-4)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 24048-14-4(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless to pale yellowish liquid

InChI:InChI=1/C14H26O/c1-12(2)7-5-8-13(3)9-6-10-14(4)11-15/h7,9,14-15H,5-6,8,10-11H2,1-4H3/b13-9+/t14-/m1/s1

Upstream product

• 22339-13-5 (E)-9-iodo-2,6-dimethylnona-2,6-diene 
• 108-05-4 vinyl acetate 
• 24120-53-4 2,6-Dimethyl-2,6-undecadiene-10-ene 
• 75-24-1 trimethylaluminum 
• 128419-46-5 2-((E)-(R)-2,6,10-Trimethyl-undeca-5,9-dienyloxy)-tetrahydro-pyran 
• 25501-67-1 2-Ethoxycarbonyl-6,10-dimethylundeca-5,9-dien-1-saeure-ethylester 
• 996-82-7 sodium diethylmalonate 
• 127483-90-3 2-((E)-(R)-2,6,10-Trimethyl-4-phenylsulfanyl-undeca-5,9-dienyloxy)-tetrahydro-pyran 
• 198268-26-7 (2R,5E,9E)-N-[(1S,2S)-2-hydroxy-1-methyl-2-phenylethyl]-2,6,10,N-tetramethylundeca-5,9-dienamide 
• 24405-96-7 diethyl (E)-2-(4,8-dimethylnona-3,7-dien-1-yl)-2-methylmalonate 
• 24405-98-9 (E)-5-2,6,10-trimethyl-5,9-undecadienoic acid 
• 459-88-1 (E)-4,8-dimethylnona-3,7-dien-1-ol 

Downstream Products

• 51513-58-7 (6E)-3,7,11-trimethyl-6,10-dodecadienal 
• 1018832-07-9 (E)-(S)-2,6,10-Trimethyl-undeca-5,9-dienal 
• 24048-13-3 (R,E)-2,6,10-trimethylundeca-5,9-dienal 

Relevant articles and documents

Total Synthesis of (±)-Liphagal via Organic-Redox-Driven Palladium-Catalyzed Hydroxybenzofuran Formation

A synthetic route to liphagal, a natural PI3Kα inhibitor isolated from Aka coralliphaga, was established. The present route features an organic redox process where an alkynylquinone undergoes reductive cyclization in the presence of a hydroquinone derivative such as hydroxyquinol (1,2,4-benzenetriol) and catalytic PdCl2 to provide a substituted benzofuran suitable for accessing the natural product. The benzofuran formation takes place via the redox transformation between the alkynylquinone and the electron-rich hydroquinones followed by the concomitant Pd(II)-catalyzed oxycyclization of the resultant alkynylhydroquinone.

Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy

ZACA-lipase-catalyzed acetylation tandem reactions provide highly efficient and selective routes to either (R)- or (S)-2-methyl-1-alkanols, making, for the first time, the ZACA-based asymmetric synthesis of 2-methyl-1-alkanols widely applicable and satisfactory.

Synthesis and evaluation of aziridine analogues of presqualene diphosphate as squalene synthase inhibitors

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