24165-06-8

Basic information

• Product Name: (1Z)-5,6-dibromocyclooctene
• CAS NO: 24165-06-8
• Molecular Formula: C₈H₁₂Br₂
• Molecular Weight: 267.9889
• Mol File: 24165-06-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 261.2°C at 760 mmHg
• Flash Point: 124.6°C
• Density: 1.634g/cm³
• Vapor Pressure: 0.019mmHg at 25°C
• Refractive Index: 1.547
• CAS DataBase Reference: (1Z)-5,6-dibromocyclooctene(CAS DataBase Reference)
• NIST Chemistry Reference: (1Z)-5,6-dibromocyclooctene(24165-06-8)
• EPA Substance Registry System: (1Z)-5,6-dibromocyclooctene(24165-06-8)

Safety Data

• Hazardous Substances Data: 24165-06-8(Hazardous Substances Data)

Usage

General Description

(1Z)-5,6-dibromocyclooctene is a chemical compound with the molecular formula C8H12Br2. It is a cycloalkene derivative with two bromine atoms attached to the cyclooctene ring. (1Z)-5,6-dibromocyclooctene is commonly used in organic chemistry for various purposes, including as a building block for the synthesis of more complex organic compounds. Its structural arrangement, with the bromine atoms attached to the cyclooctene ring, makes it useful for the creation of diverse chemical structures. Additionally, (1Z)-5,6-dibromocyclooctene has been studied in the context of chemical reactions and mechanisms, further contributing to its importance in the field of organic chemistry.

Upstream product

• 1552-12-1 1,5-cis,cis-cyclooctadiene 
• 5259-72-3 cyclo-octa-1,5-diene 

Downstream Products

• 66633-23-6 (Z)-cyclooct-1-ene-5-yne 
• 57559-44-1 1-bromo-1,5-cyclooctadiene 
• 1392323-39-5 C₂₁H₂₀BrNO 
• 1392323-14-6 C₂₁H₂₁NO 

Relevant articles and documents

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Golden Opportunity: A Clickable Azide-Functionalized [Au25(SR)18]- Nanocluster Platform for Interfacial Surface Modifications

Ultrasmall atomically precise monolayer-protected gold thiolate nanoclusters are an intensely researched nanomaterial framework, but there is a lack of a system that can be directly synthesized and undergo interfacial surface chemistry. We report an [Au25(SCH2CH2-p-C6H4-N3)18]- nanocluster platform with azide moieties appended onto each surface ligand. The structure of this surface reactive cluster has been confirmed by single-crystal X-ray crystallography, mass spectrometry and ultraviolet visible, infrared and nuclear magnetic resonance spectroscopies. We show that all surface azide moieties are amenable to cluster-surface strain-promoted alkyne-azide cycloaddition chemistry with a strained cyclooctyne, opening this as a new platform to allow functional, postassembly surface modifications to this very prominent nanocluster.

ENTHALPIES OF THE REACTIONS OF BROMINE WITH SOME UNSATURATED HYDROCARBONS

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