24165-64-8

Basic information

• Product Name: Benzenemethanol, 3-methyl-a-2-propenyl-
• CAS NO: 24165-64-8
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 24165-64-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 3-methyl-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3-methyl-a-2-propenyl-(24165-64-8)
• EPA Substance Registry System: Benzenemethanol, 3-methyl-a-2-propenyl-(24165-64-8)

Safety Data

• Hazardous Substances Data: 24165-64-8(Hazardous Substances Data)

Upstream product

• 2622-05-1 allylmagnesium bromide 
• 620-23-5 m-tolyl aldehyde 
• 1162681-61-9 4-(3-methylphenyl)-4-trimethylsiloxy-1-butene 
• 762-72-1 allyl-trimethyl-silane 
• 13911-49-4 allyltriethyllead 
• 1730-25-2 allylmagnesium bromide 
• 24850-33-7 allyltributylstanane 
• 100-52-7 benzaldehyde 
• 591-87-7 Allyl acetate 

Downstream Products

• 1453859-75-0 (Z)-1-m-tolylbut-2-en-1-one 
• 944344-73-4 (E)-1-(3-tolyl)but-2-en-1-one 
• 1250909-95-5 1-(m-tolyl)but-3-en-1-one 
• 1620206-34-9 (E)-N-(1-bromo-4-(m-tolyl)but-3-en-2-yl)-2,2,2-trichloroacetamide 
• 1616603-18-9 C₁₃H₁₅NO₂ 
• 73794-59-9 2-(3-Methylphenyl)pyrrol 
• 1439921-55-7 1-(m-tolyl)but-3-en-1-one oxime 
• 1574316-47-4 C₁₁H₁₂N₄O 
• 1162681-61-9 4-(3-methylphenyl)-4-trimethylsiloxy-1-butene 
• 1335143-95-7 6-m-tolyl-5,6-dihydro-2H-pyran-2-one 

Relevant articles and documents

Visible Light-Promoted Recyclable Carbon Nitride-Catalyzed Dioxygenation of β,γ-Unsaturated Oximes

A visible-light-induced dioxygenation of β,γ-unsaturated oximes for the synthesis of diverse useful isoxazolines bearing a hydroxyl moiety was developed by employing graphitic carbon nitride (g-C3N4) as a heterogeneous photocatalyst under an air atmosphere. Noted that, the eminent advantages of this metal-free protocol include step economy, easy operation, a recyclable photocatalyst, external reductant-/oxidant-free and mild reaction conditions. Additionally, mechanistic studies indicated hydroxyl radical was generated under the photocatalysis of g-C3N4.

Synthesis of Z-alkenes from Rh(I)-catalyzed olefin isomerization of β,γ-unsaturated ketones

Developing olefin isomerization reactions to reach kinetically controlled Z-alkenes is challenging because formation of trans-alkenes is thermodynamically favored under the traditional catalytic conditions using acids, bases, or transition metals as the catalysts. A new synthesis of Z-alkenes from Rh(I)-catalyzed olefin isomerization of β,γ-unsaturated ketones to α,β-unsaturated ketones was developed, providing an easy and efficient way to access various Z-enones.

Mesoporous aluminosilicate-catalyzed allylation of carbonyl compounds and acetals

A mesoporous aluminosilicate (Al-MCM-41) was found to be an effective heterogeneous catalyst for the reaction of both carbonyl compounds and acetals with allylsilanes to afford the corresponding homoallyl silyl ethers and homoallyl alkyl ethers, respectively. Both the mesoporous structure and the presence of aluminum moiety were indispensable for the high catalytic activity of Al-MCM-41. Moreover, Al-MCM-41 could catalyze the reaction of acetals chemoselectively in the presence of the corresponding carbonyl compounds. The solid acid catalyst Al-MCM-41 could be recovered easily by filtration and could be reused three times without a significant loss of catalytic activity.