24173-71-5Relevant articles and documents
Synthesis of Caryophyllane Oximes and Hydrazone and Their O- and N-Acylated Derivatives
Gyrdymova, Yu. V.,Rubtsova,Slepukhin
, p. 72 - 78 (2021/02/01)
Kobusone oxime and hydrazone were synthesized for the first time in yields of 78 and 71%, respectively, via condensation of the sesquiterpene ketone kobusone, which was prepared by oxidation of caryophyllene oxide, with hydroxylamine and hydrazine. Acylation of the caryophyllane oxime and hydrazone produced series of O- and N-derivatives in preparative yields up to 90%. The molecular structures of the acyloximes and acetylhydrazone were established by X-ray crystal structure analyses.
Meroterpene-like compounds derived from β-caryophyllene as potent α-glucosidase inhibitors
Ma, Shuang-Jiang,Yu, Jie,Yan, Da-Wei,Wang, Da-Cheng,Gao, Jin-Ming,Zhang, Qiang
supporting information, p. 9454 - 9460 (2019/01/03)
Meroterpenoids isolated from guava (Psidium guajava) and Rhodomyrtus tomentosa possess special skeletons which incorporate terpenoids with phloroglucinol derivatives. Most of these meroterpenoids showed high cytotoxicity against cancer cell lines. However
Convenient synthesis of deuterium labelled sesquiterpenes
Duhamel, Nina,Martin, Damian,Larcher, Roberto,Fedrizzi, Bruno,Barker, David
supporting information, p. 4496 - 4499 (2016/09/14)
Sesquiterpenes are an important class of molecules, with roles ranging from pollination and signalling to defense mechanisms. Despite their apparent importance, the limited number of commercial standards has hindered their study and precise quantification. Herein, we report the syntheses of fourteen labelled sesquiterpenes with a high level of deuterium incorporation (>95%) for applications in MS-based studies.